256519-92-3Relevant articles and documents
Helical twist sense bias in oligo(phenylene ethynylene)s induced by an optically active flexible tether
Gin, Mary S.,Moore, Jeffrey S.
, p. 135 - 138 (2000)
(equation presented) A series of tethered phenylene ethynylene oligomers, which undergo a solvent-dependent conformational transition from a random coil to a helix, has been synthesized. The use of trimethylsilyl ether protecting groups on the (+)-tartaric acid-derived tether results in the formation of helices with a large twist sense bias. In contrast, an isopropylidene ketal protecting group or no protecting group is not only ineffective at helical discrimination but may even inhibit helix formation.