25662-14-0

Upstream product

• 1729-67-5 Methyl 2,3-dibromopropionate 
• 75-64-9 tert-butylamine 

Downstream Products

• 1268341-29-2 C₁₇H₂₂F₅NO₂S 
• 1174209-72-3 methyl 1-tert-butyl-4-pentafluorosulfanyl-3-phenyl-2,5-dihydro-2H-pyrrole-2-carboxylate 
• 1268341-27-0 C₁₈H₂₄F₅NO₂S 
• 100819-44-1 C₂₂H₃₂N₂O₄ 
• 100819-45-2 1-tert-Butyl-aziridine-2-carboxylic acid benzylamide 
• 92236-89-0 3,4-Difluoro-1-t-butyl-pyrrole 
• 109849-70-9 rac-S-phenyl l-1-(tert-butyl)-2-(α-hydroxybenzyl)aziridine-2-carbothioate 
• 109849-70-9 rac-S-phenyl u-1-(tert-butyl)-2-(α-hydroxybenzyl)aziridine-2-carbothioate 
• 109849-73-2 rac-S-phenyl 1-(tert-butyl)-2-(2-nitro-1-phenylethyl)aziridine-2-carbothioate 
• 109849-68-5 rac-S-phenyl 1-(tert-butyl)-2-(1-hydroxyethyl)aziridine-2-carbothioate 
• 109849-72-1 rac-1-(tert-butyl)-6-phenyl-1-aza-5-oxaspiro<2,3>-hexan-4-one 
• 109849-75-4 rac-S-phenyl 1-(tert-butyl)-2-methylaziridine-2-carbothioate 
• 54912-92-4 N-t-butyl aziridine carboxylic acid phenylthiol ester 

Relevant academic research and scientific papers

Isolation and characterization of [5,6]-pyrrolidino-Sc3N@Ih-C80 diastereomers

Reactions of Sc3N@Ih-C80 with aziridine derivatives were conducted to afford the corresponding mono-adducts. A pair of diastereomers of the mono-adduct [5,6]-pyrrolidino-Sc3N@Ih-C80 was isolated and characterized by means of mass spectrometry, vis-NIR absorption spectroscopy, and electrochemical measurements. Structural analysis of the mono-adducts was conducted by NMR and single-crystal X-ray structure determinations. This journal is

Conformational Analysis of the Cyclopropylacyl, Oxiranylacyl, and Aziridinylacyl Radicals by Electron Spin Resonance Spectroscopy

A series of ring-substituted cyclopropylacyl, oxiran-2-ylacyl, and aziridin-2-ylacyl radicals have been prepared principally by the reaction of photolytically generated t-butoxyl radicals with the corresponding aldehydes.The e.s.r. spectra show that the cyclopropylacyl ?-radicals exist in s-cis- and s-trans-conformations of approximately equal stability, in which the plane of the acyl group bisects the ring (as it does in the parent aldehyde), and simulation of the spectra through the region of intermediate rates of exchange show that the barrier to rotation is ca. 17.5 kJ*mol-1.The behaviour of the trans-2-ethoxycarbonylcyclopropylacyl and 2,2-dimethylcyclopropylacyl radicals is similar.The oxiranylacyl and trans-3-methyloxiranylacyl radicals exist in the same two conformations with a rather lower barrier, and the N-alkylaziridinylacyl radicals appear to have a lower barrier still.