257627-67-1

Basic information

• Product Name: tert-butyl-(2,2-dimethoxypropoxy)diphenylsilane
• Synonyms: tert-butyl-(2,2-dimethoxypropoxy)diphenylsilane
• CAS NO: 257627-67-1
• Molecular Weight: 358.553
• Mol File: 257627-67-1.mol

Chemical Properties

• CAS DataBase Reference: tert-butyl-(2,2-dimethoxypropoxy)diphenylsilane(CAS DataBase Reference)
• NIST Chemistry Reference: tert-butyl-(2,2-dimethoxypropoxy)diphenylsilane(257627-67-1)
• EPA Substance Registry System: tert-butyl-(2,2-dimethoxypropoxy)diphenylsilane(257627-67-1)

Safety Data

• Hazardous Substances Data: 257627-67-1(Hazardous Substances Data)

Upstream product

• 118171-02-1 1-(tert-butyldiphenylsilyloxy)-2-propanone 
• 149-73-5 trimethyl orthoformate 

Downstream Products

• 257627-69-3 (2S,3S,4S,5R)-1-[5-((tert-butyldiphenylsiloxy)methyl)-4-(dimethylphenylsilyl)-2,3,5-trimethyltetrahydrofuran-3-yl]ethanone 
• 257627-70-6 (2S,3S,4S,5R)-1-(4-dimethylphenylsilyl-5-hydroxymethyl-2,3,5-trimethyltetra-hydrofuran-3-yl)ethanone 
• 257627-68-2 (S)-2-(tert-Butyl-diphenyl-silanyloxymethyl)-4-[(E)-2-(dimethyl-phenyl-silanyl)-1-methyl-vinyl]-2,4,5-trimethyl-[1,3]dioxolane 

Relevant articles and documents

Stereoselection in the prins-pinacol synthesis of 2,2-disubstituted 4-acyltetrahydrofurans. Enantioselective synthesis of (-)-citreoviral.

[reaction: see text] The condensation of allylic diols with unsymmetrical ketones proceeds with high stereoselection to form 2,2-disubstituted 4-acyltetrahydrofurans when the alpha-substituents of the ketone differ substantially in size. A Prins-pinacol c