25772-36-5Relevant academic research and scientific papers
Photolytic release of carboxylic acids using linked donor-acceptor molecules: Direct versus mediated photoinduced electron transfer to N-alkyl-4-picolinium esters
Sundararajan, Chitra,Falvey, Daniel E.
, p. 2631 - 2634 (2005)
(Chemical Equation Presented) Efficient photorelease (Φ = 0.7) of carboxylic acids is achieved with a covalenlly linked mediator (benzophenone) protecting group (N-alkyl-4-picolinium ester) molecule. The mechanism involves initial photoreduction of the mediator, followed by rapid electron transfer to the protecting group.
AROMATIC KETONES EITH TERMINAL VINYL GROUPS
Uvarova, L. R.,Burykina, L. K.,Zubareva, M. M.,Polyanskii, I. D.
, p. 1346 - 1349 (2007/10/02)
The Friedel-Crafts acylation of a hydrocarbon by an acylating agent containing bromoalkyl substituents gave a series of new ketones.Their subsequent dehydrobromination with potassium tert-butoxide gave high yields of aromatic ketones containing terminal vinyl groups.
