25784-84-3

Basic information

• Product Name: 2-PROPANONE, 1-[(4-METHOXYPHENYL)THIO]-
• Synonyms: 2-PROPANONE, 1-[(4-METHOXYPHENYL)THIO]-;1-((4-Methoxyphenyl)thio)propan-2-one
• CAS NO: 25784-84-3
• Molecular Formula: C₁₀H₁₂O₂S
• Molecular Weight: 196.27
• Mol File: 25784-84-3.mol
• Article Data: 16

Chemical Properties

• Boiling Point: 300.291°C at 760 mmHg
• Flash Point: 139.061°C
• Appearance: /
• Density: 1.135g/cm³
• Vapor Pressure: 0.001mmHg at 25°C
• Refractive Index: 1.551
• CAS DataBase Reference: 2-PROPANONE, 1-[(4-METHOXYPHENYL)THIO]-(CAS DataBase Reference)
• NIST Chemistry Reference: 2-PROPANONE, 1-[(4-METHOXYPHENYL)THIO]-(25784-84-3)
• EPA Substance Registry System: 2-PROPANONE, 1-[(4-METHOXYPHENYL)THIO]-(25784-84-3)

Safety Data

• Hazardous Substances Data: 25784-84-3(Hazardous Substances Data)

Usage

InChI:InChI=1/C10H12O2S/c1-8(11)7-13-10-5-3-9(12-2)4-6-10/h3-6H,7H2,1-2H3

Upstream product

• 696-63-9 4-Methoxybenzenethiol 
• 1219622-14-6 S-adenosyl-S-(propan-2-one)-L-methionine 
• 2564-83-2 2,2,6,6-Tetramethyl-1-piperidinyloxy free radical 
• 5335-87-5 4,4'-dimethoxyphenyl disulfide 
• 598-31-2 1-bromoacetone 
• 67-64-1 acetone 
• 104-92-7 1-bromo-4-methoxy-benzene 
• 78-95-5 chloroacetone 

Downstream Products

• 54730-14-2 5-[(4-methoxy-phenylsulfanyl)-methyl]-5-methyl-imidazolidine-2,4-dione 
• 675576-53-1 (S)-1-(4-methoxyphenyl)thiopropan-2-ol 
• 14065-14-6 2,4'-Dimethoxy-5-nitro-diphenylsulfid 
• 14065-23-7 1-methoxy-2-[(4-methoxyphenyl)thio]benzene 
• 117097-84-4 (S)-1-(p-methoxyphenylsulfinyl)-2-propanone 
• 117097-81-1 (R)-1-(p-methoxyphenylsulfinyl)-2-propanone 
• 691357-06-9 6,7-difluoro-2-(4-methoxy-phenylsulfanyl)-3-methyl-quinoxaline 1,4-dioxide 
• 14065-09-9 4'-Methoxy-2-hydroxy-5-nitro-diphenylsulfid 
• 127642-03-9 (p-methoxyphenylsulfinyl)acetone 
• 25784-98-9 5-methoxy-3-methylbenzo[b]thiophene 

Relevant articles and documents

Total Synthesis of the Reported Structure of Stresgenin B Enabled by the Diastereoselective Cyanation of an Oxocarbenium

We report the first total synthesis of the reported structure of the heat shock protein expression inhibitor stresgenin B. The synthesis features (1) diastereoselective cyanation of an oxocarbenium intermediate en route to the synthetically challenging α-

Synthesis of α-arylthioacetones using TEMPO as the: C 3 synthon via a reaction cascade of sequential oxidation, skeletal rearrangement and C-S bond formation

Here, we present an unprecedented pathway to α-sulfenylated carbonyl compounds from commercially available thiols and universally employed TEMPO and its analogues, which act as C3 synthons through skeletal rearrangement under simple and metal-f

Fe-Mediated S-S Bond Cleavage and Its Application in the Synthesis of α-Arylthio Carbonyl Compounds

In the presence of iron dust, diaryl disulfides react with α-bromo carbonyl compounds to obtain α-arylthio carbonyl compounds in good yield at 90 °C under an N2 atmosphere, using commercial dimethylformamide (DMF) as solvent. The possible reaction mechanism is that the disulfide is reduced by iron dust to give ArSFeSAr and then reacted with α-bromo carbonyl compounds to give product α-arylthio carbonyl compounds and FeBr2.