25856-04-6Relevant academic research and scientific papers
Process for preparing vinyl substituted beta-diketones
-
Page/Page column 9, (2008/06/13)
A process for preparing vinyl substituted beta-diketones includes reacting a halogen-containing beta-diketone with an olefin in a reaction zone under Heck coupling reaction conditions in the presence of a catalyst, a base, and an organic phosphine to provide a vinyl substituted beta-diketone product.
Synthesis of vinyl-substituted β-diketones for polymerizable metal complexes
Southard, Glen E.,Murray, George M.
, p. 9036 - 9039 (2007/10/03)
Polymerizable β-diketones for application to metal ion coordination have been prepared and characterized. Bromine-substituted β-diketones were synthesized under Claisen-Schmidt-type condensation conditions. Vinyl groups were substituted for the halide by
