25862-15-1Relevant academic research and scientific papers
A general and efficient method to convert selenides into selenones by using HOF·CH3CN
Potash, Shay,Rozen, Shlomo
, p. 5574 - 5579 (2013/09/12)
A general route for the preparation of selenones (R2SeO 2) is presented. This task is achieved through the quick and high-yielding reaction of selenides (R2Se) with HOF·CH 3CN. The reaction tolerates some elusiv
Synthesis of Selenoxides by Oxidation of Selenides with t-Butyl Hypochlorite, and Its Application for Synthesis of Optically Active Selenoxide
Kobayashi, Michio,Ohkubo, Hiromi,Shimizu, Toshio
, p. 503 - 506 (2007/10/02)
An effective synthesis of selenoxides by the oxidation of selenides with t-butyl hypochlorite in the presence of methanol and pyridine followed by hydrolysis is described.This oxidation method is particularly effective for the oxidation of selenides which possess electron-withdrawing groups.A synthesis of partially optically active selenoxide with bulky substituents can be achieved using a novel oxidation method.
