25882-75-1Relevant articles and documents
Reductive Photocarboxylation of Aromatic Hydrocarbons
Tazuke, Shigeo,Kazama, Shingo,Kitamura, Noboru
, p. 4548 - 4553 (2007/10/02)
Photoirradiation of aromatic hydrocarbons such as phenanthrene, anthracene, or pyrene in the presence of an amine and carbon dioxide in dipolar aprotic solvents resulted in reductive carboxylation of the hydrocarbon.The reaction was considered to proceed
Photochemical Reactions of Aromatic Compounds. XXXVI. The Photoreactions of Anthracene with Some Selected Tertiary Aromatic Amines in Polar Media
Yasuda, Masahide,Pac, Chyongjin,Sakurai, Hiroshi
, p. 2352 - 2355 (2007/10/02)
The photoreaction of anthracene witn N,N-dimethylaniline in acetonitrile gave 9-(p-dimethylaminophenyl)-9,10-dihydroanthracene in a good yield, along with 9,10-dihydroanthracene and 9,9',10,10'-tetrahydro-9,9'-bianthryl.This photoreaction was found to depend on the polarity of the solvent as well as on its protic or aprotic nature.With N,N-dimethyl-m-toluidine, a similar 1 : 1 adduct was obtained, while the reduced anthracenes were mainly formed in the photoreactions with N,N-dimethyl-o- and p-toluidines.The mechanisms were discussed in terms of the dissociation into the ion radical as well as their reactivities.