258822-89-8

Basic information

• Product Name: 2-Thiazolidinimine, N-cyano-3-(phenylthio)-
• CAS NO: 258822-89-8
• Molecular Formula: C10H9N3S2
• Molecular Weight: 235.334
• Mol File: 258822-89-8.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 2-Thiazolidinimine, N-cyano-3-(phenylthio)-(CAS DataBase Reference)
• NIST Chemistry Reference: 2-Thiazolidinimine, N-cyano-3-(phenylthio)-(258822-89-8)
• EPA Substance Registry System: 2-Thiazolidinimine, N-cyano-3-(phenylthio)-(258822-89-8)

Safety Data

• Hazardous Substances Data: 258822-89-8(Hazardous Substances Data)

Upstream product

• 26364-65-8 2-(N-cyanoimino)thiazolidine 
• 931-59-9 benzenesulfenyl chloride 

Downstream Products

• 20841-46-7 2-(phenylthio)-3,4-dihydronaphthalen-1(2H)-one 
• 76643-99-7 2,2-bis(phenylthio)-1-tetralone 
• 19117-31-8 N-(phenylthio)-N-(tert-butyl)amine 
• 4032-81-9 ethyl phenyl disulfide 
• 52190-41-7 2-phenylsulfanylcycloheptanone 
• 23837-23-2 N-Benzyl-benzolsulfensaeureamid 
• 14933-91-6 N-phenyl-benzenesulphenamide 
• 52190-40-6 2-(phenylthio)cyclopentanone 
• 84978-78-9 2,2-Bis-(phenylthio)-cyclopentanon 
• 24380-80-1 N-ethyl-S-phenylsulfenamide 
• 36476-32-1 Ethyl-α,α'-bis(phenylthio)acetoacetat 
• 27872-73-7 2-phenylsulfanyl-acetoacetic acid ethyl ester 
• 110452-14-7 2-phenylthiocyclohexanone 
• 35874-99-8 2,2-Bis(phenylthio)cyclohexanon 

Relevant articles and documents

A new sulfenylation reagent, 3-phenylsulfenyl-2-(N- cyanoimino)thiazolidine, and its optically active version

We have developed a new sulfenylation reagent, 3-phenylsulfenyl-2-(N- cyanoimino)thiazolidine 3, that is readily available and stable upon storage. Compound 3 easily reacts with amines or thiols to give the corresponding sulfenamides or asymmetrical disulfides in excellent yields. It was also found that the α-sulfenylation reaction of carbonyl compounds with 3 proceeds smoothly. Furthermore, optically active 4-diphenylmethyl derivative 4 was synthesized as an asymmetric sulfenylation reagent, which realized 96% e.e. upon α-sulfenylation of a cyclic β-keto ester.