258826-42-5

Basic information

• Product Name: N-(4-methoxybenzyl)-L-valine
• Synonyms: N-(4-methoxybenzyl)-L-valine
• CAS NO: 258826-42-5
• Molecular Weight: 237.299
• Mol File: 258826-42-5.mol

Chemical Properties

• CAS DataBase Reference: N-(4-methoxybenzyl)-L-valine(CAS DataBase Reference)
• NIST Chemistry Reference: N-(4-methoxybenzyl)-L-valine(258826-42-5)
• EPA Substance Registry System: N-(4-methoxybenzyl)-L-valine(258826-42-5)

Safety Data

• Hazardous Substances Data: 258826-42-5(Hazardous Substances Data)

Upstream product

• 123-11-5 4-methoxy-benzaldehyde 
• 72-18-4 L-valine 
• 771433-72-8 α-Isopropyl-N-<4-methoxy-benzyliden>-glycin 

Downstream Products

• 258826-43-6 (S)-2-[Benzyl-(4-methoxy-benzyl)-amino]-3-methyl-butyric acid benzyl ester 
• 916850-84-5 N-(tert-butoxycarbonyl)-N-(4-methoxybenzyl)-L-valine 
• 916850-88-9 (3S,8aS)-2-(4-methoxybenzyl)-3-isopropyloctahydropyrrolo[1,2-a]pyrazine-1,4-dione 
• 916850-86-7 N-(tert-butoxycarbonyl)-N-(4-methoxybenzyl)-L-valinyl-L-proline methyl ester 
• 258826-44-7 (S)-2-Benzylamino-3-methyl-butyric acid benzyl ester 

Relevant articles and documents

Synthesis towards complex bridged alkaloids derived from diketopiperazines: a cationic cascade approach to stephacidins, paraherquamides and related systems

Regioselective enolate formation, followed by stereoselective electrophilic quenching of unsymmetrical proline-derived diketopiperazines (DKPs), enabled the synthesis of variously substituted DKPs, including one substrate which could be further substitute

Studies towards complex bridged alkaloids: regio- and stereocontrolled enolate chemistry of 2,5-diketopiperazines

The substitution of symmetrical N-protected diketopiperazines (DKPs) via enolate intermediates has been studied. The enolate reactions were highly diastereocontrolled, leading to enantiopure DKP products if chiral amino acid precursors were employed, and

Chemoselective oxidative debenzylation of N,N-dibenzylamines

Tertiary amines incorporating two N-benzyl substituents are readily mono-debenzylated with CAN or DDQ. An N,N-dibenzyl derivative of a dienylamine with a homoallylic C-N bond is smoothly deblocked by DDQ as well, whereas CAN leads to fragmentation in this case.