258834-77-4

Basic information

• Product Name: 3,5-bis(2,2’:6’,2-terpyridyl)bromobenzene
• Synonyms: 3,5-bis(2,2’:6’,2-terpyridyl)bromobenzene
• CAS NO: 258834-77-4
• Molecular Weight: 619.523
• Mol File: 258834-77-4.mol
• Article Data: 6

Chemical Properties

• CAS DataBase Reference: 3,5-bis(2,2’:6’,2-terpyridyl)bromobenzene(CAS DataBase Reference)
• NIST Chemistry Reference: 3,5-bis(2,2’:6’,2-terpyridyl)bromobenzene(258834-77-4)
• EPA Substance Registry System: 3,5-bis(2,2’:6’,2-terpyridyl)bromobenzene(258834-77-4)

Safety Data

• Hazardous Substances Data: 258834-77-4(Hazardous Substances Data)

Upstream product

• 1122-62-9 2-acetylpyridine 
• 120173-41-3 5-bromobenzene-1,3-dicarbaldehyde 

Relevant articles and documents

Hexagonal terpyridine-ruthenium and -iron macrocyclic complexes by stepwise and self-assembly procedures

Methods for the self-assembly, as well as directed construction, of hexaruthenium metallomacrocycles employing bisterpyridine building blocks are described. Self-assembly is effected by a combination of equimolar mixtures of bismetalated and nonmetalated

Multi-terpyridyl metal organic ligand compound, five-membered flower ring-shaped supramolecule assembled thereby, and preparation

The invention discloses synthesis method of a five-membered flower cyclic supramolecule based on terpyridyl metal coordination. The supermolecule is a giant five-membered flower ring-shaped supermolecule formed by self-driving a ligand containing a plurality of terpyridyl and metal ruthenium and transition metal ions in a solvent, wherein the ligand and the transition metal can accurately react togenerate a single pentamer product without generation of other byproducts; then structural characterization and molecular weight determination are carried out on the ligand and a final assembly product through nuclear magnetism, mass spectrometry, scanning electron microscopy and other tests. The supermolecule has large molecular weight and good solubility, the molecular structure has symmetry and aesthetic properties, and gelation can be realized.

Efficient Self-Assembly of Di-, Tri-, Tetra-, and Hexavalent Hosts with Predefined Geometries for the Investigation of Multivalency

Coordination-driven self-assembly of differently shaped di- to hexavalent crown-ether host molecules is described. A series of [21]crown-7- and [24]crown-8-substituted bipyridine and terpyridine ligands was synthetized in a "toolbox" approach. Subsequent