2589-56-2Relevant articles and documents
ELECTRON-TRANSFER PROCESSES: MECHANISMS OF OXIDATION OF ETHERS AND ESTERS BY SILVER-CATALYZED PEROXYDISULPHATE
Minisci, Francesco,Coppa, Fausta,Fontana, Francesca,Zhao, Lihua
, p. 613 - 616 (2007/10/02)
Nucleophilic carbon-centred radicals, generated from the oxidation of diethyl ether, ethyl acetate, propyl acetate, ethyl propionate, diethyl oxalate and 2-phenylethyl acetate by silver-catalyzed decomposition of peroxydisulphate, have been trapped, mostly by naphthoquinone and in a few cases by protonated quinoline. Characterization of the intermediate radicals allows the rationalization of the mechanism of these oxidations, which are likely to occur through an initial electron-transfer step by Ag(II).