259136-26-0Relevant academic research and scientific papers
Synthesis and reactivities of dihydrosilanes tethered with two thioether moieties
Takeda, Nobuhiro,Nakamura, Tetsu,Imamura, Ayako,Unno, Masafumi
experimental part, p. 438 - 445 (2012/01/06)
Dihydrosilanes tethered with two thioether moieties, [2-(RSCH 2)C6H4]2SiH2(1a: R = t-Bu; 1b: R = i-Pr; 1c: R = Ph), were synthesized. Dihydrosilane 1b did not react with methanol, benzaldehyde, and ca
Synthesis and complexation of a new tripodal tetradentate ligand, a silyl ligand tethered with three thioether moieties
Takeda, Nobuhiro,Watanabe, Daisuke,Nakamura, Tetsu,Unno, Masafumi
supporting information; experimental part, p. 2839 - 2841 (2010/10/04)
Iridium(III) and platinum(II) complexes with a new tripodal tetradentate ligand, tris[2-(tert-butylthiomethyl)-phenyl]silyl were synthesized. In addition, reaction of tris-(2-((tert-butylthio)methyl)phenyl)silane with [PdCl2(PhCN)2]
PROCESS FOR PRODUCING CYCLIC THIOETHER AND SYNTHETIC INTERMEDIATE THEREOF
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Page/Page column 21-22, (2010/02/11)
The present invention provides a process for producing cyclic thioether compounds and their synthetic intermediates.[Means for Solution]A compound represented by general formula (5): [wherein G1: alkylene, R1: a thiol protecting grou
Highly Flexible Synthetic Routes to Functionalized Phospholanes from Carbohydrates
Yan, Yuan-Yong,RajanBabu
, p. 900 - 906 (2007/10/03)
Highly functionalized phospholanes 15, 17, and 26 and the corresponding diastereomers in which the configurations of the phospholane carbon-2 and carbon-5 are inverted can be readily prepared from D-mannitol by displacement of the appropriate dimesylate or cyclic sulfate with dilithium-phosphide reagents. The diols from which these ligands are prepared can also be converted into diarylphosphinite ligands. A route to related monophosphines bearing hemilabile tert-butylthio groups is also described. Complexes of these ligands and of related deprotected derivatives are potentially useful for enantioselective catalysis in organic and aqueous media.
