25926-16-3Relevant academic research and scientific papers
Synthesis and kinetic study of a series of chloro- and m-carboxypyridium triazinyl reactive dyes
Huang, Huei-Chin,Wu, Chun-Guey
, (2021)
Five monochloro-s-triazinyl reactive dyes (MCT) and five m-carboxypyridium-s-triazinyl reactive dyes (NTR) were synthesised with the same red chromophore bearing an –NHCN, –OCH3, –CH3NSO2CH3, –N-methyl phenyl or –OH group as ‘second-leg’ substituents. A kinetic study of the hydrolysis of these dyes was conducted, and the rate constant (kobs) and half-life time values were determined. The kobs of the MCT and NTR dyes was found to follow the order –OCH3 > –CH3NSO2CH3 > –N-methyl phenyl > –NHCN > –OH, which was approximately in agreement with the values obtained for the Hammett substituent constants. Overall, the higher the electron-donating property of the substituent on meta-position to the leaving group in the triazine ring, the lower the hydrolysis rate constant.
Synthesis and applications of triazinyl based reactive red dyes
Bhatti, Khalid Pervez,Zuber, Muhammad
experimental part, p. 263 - 268 (2012/05/04)
A series of mono and di-chlorotriazinyl based reactive red dyes were synthesized containing the common H-acid nucleus with different reactive coupling groups-sulfanilic acid, metanilic acid, orthanilic acid, anthranilic acid and tobias acid. These syntheses were monitored by thin-layer chromatography (TLC). The solubility of the synthesized dyes was investigated in water at various temperatures. Their Spectrophotometric data indicated significant alteration in their emax values which corresponded to the nature of the substituents (-SO3H, -COOH) of the diazocomponents used. The bi-functional bridged reactive dyes, containing the derivatives of anthranilic acid (KPR-15, KPR-16) showed the highest secondary exhaustion degree from the dyebath while derivatives of tobias acid showed the highest fixation ratio (KPR-19, KPR-20). The improved fastness properties of perspiration, washing and light were investigated. The fabrics with an intense color and good characteristics were obtained, thus presenting a possibility for the extension of usually applied reactive red dyes.
Fiber reactive dyestuffs
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Page/Page column 20, (2010/11/24)
A fiber reactive dyestuff of the following formula (I) wherein the definition of D, R, R1, R2, X and Z have the same meaning as given in the specification. The fiber reactive dyestuff of the present invention is suitable for dyeing and printing on cellulose fiber or fiber materials containing cellulose. Dyed material with various excellent properties in dyed color can be obtained, showing especially outstanding performance in the property of wash fastness, build-up and chlorine fastness.
Environmental protection series of reactive dyestuffs and their use
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Page/Page column 9-10, (2010/02/14)
An environmental protection reactive dyestuff of the following formula (I) is disclosed, wherein R1, R2, D, M are defined as in the specification. The dyestuff of the invention is distinguished by a high fixation and a very good build-up. It is distinguished also by a green environmental protection and a low salt, a low base, a high exhaustion, non-contain heavy metal and halogen atoms, and it has fiber-reactive properties and is very highly suitable for dyeing and printing of materials containing either cellulose fibers, such as cotton, synthetic cotton, hemp, and synthetic hemp, or amide containing fibers such as wool and nylon.
Bridged disazo compounds
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Example 146, (2008/06/13)
Compounds of formula (I) with the meanings of D, R1, R2, X and Y as given in claim 1 can be used as paper dyes or direct dyes or for the preparation of ink-jet inks.
