259654-70-1Relevant academic research and scientific papers
Thiocarbonyl compounds as regulating reagent in the radical addition of tertiary amines with alkenes using photoelectron transfer conditions
Harakat, Dominique,Pesch, Jens,Marinkovic, Sinia,Hoffmann, Norbert
, p. 1202 - 1205 (2006)
The effect of thiocarbonyl compound addition to a reaction mixture on the efficiency of the photoinduced radical addition of tertiary amines to oleifinic double bonds was investigated. Various aromatic ketones in combination with different tertiary amines
Stereoselective radical addition of tertiary amines to (5R)-5- menthyloxy-2[5H]-furanone: Application to the enantioselective synthesis of (-)-isoretronecanol and (+)-labumine
Bertrand, Samuel,Hoffmann, Norbert,Pete, Jean-Pierre
, p. 3173 - 3174 (1999)
The adducts of a stereoselective radical addition of tertiary amines with (5R)-5-menthyloxy-2[5H]-furanone were transformed very efficiently into enantiomerically pure pyrrolizidine and indolizidine alkaloids, through a three steps sequence.
Efficient radical addition of tertiary amines to electron-deficient alkenes using semiconductors as photochemical sensitisers
Marinkovic,Hoffmann
, p. 1576 - 1577 (2007/10/03)
Tertiary amines can be added to electron-deficient alkenes with yields up to 98% in a radical chain reaction initiated by a photochemical electron transfer using inorganic semiconductors like TiO2 as sensitiser.
