259670-50-3

Basic information

• Product Name: meso-3,4-di-t-butyldiphenylsiloxy-8-oxabicyclo[4.3.0]nonane
• Synonyms: meso-3,4-di-t-butyldiphenylsiloxy-8-oxabicyclo[4.3.0]nonane
• CAS NO: 259670-50-3
• Molecular Weight: 635.006
• Mol File: 259670-50-3.mol

Chemical Properties

• CAS DataBase Reference: meso-3,4-di-t-butyldiphenylsiloxy-8-oxabicyclo[4.3.0]nonane(CAS DataBase Reference)
• NIST Chemistry Reference: meso-3,4-di-t-butyldiphenylsiloxy-8-oxabicyclo[4.3.0]nonane(259670-50-3)
• EPA Substance Registry System: meso-3,4-di-t-butyldiphenylsiloxy-8-oxabicyclo[4.3.0]nonane(259670-50-3)

Safety Data

• Hazardous Substances Data: 259670-50-3(Hazardous Substances Data)

Upstream product

• 935-79-5 cis-1,2,3,6-tetrahydrophthalic anhydride 
• 3470-42-6 cis-8-oxabicyclo<4.3.0>non-3-ene 
• 58479-61-1 tert-butylchlorodiphenylsilane 
• 260259-08-3 (3ar,7ac)-octahydro-isobenzofuran-5c,6c-diol 
• 439919-46-7 cis-1,6-dihydroxymethyl-3-cyclohexene 

Relevant articles and documents

Application of oxidative desymmetrization of meso-tetrahydrofurans: Syntheses of functionalized chiral building blocks and of (-)-alloyohimbane

Oxidative desymmetrization of oxygen functionalized mesotetrahydrofurans was successfully achieved (up to 87% ee) through (salen)manganese(III) catalyzed enantiotopic selective C-H oxidation. The enantioselective synthesis of (-)-alloyohimbane (12) has also been achieved in a short step by using oxidative desymmetrization of meso-tetrahydrofuran as the key step.