259670-59-2

Upstream product

• 3470-42-6 cis-8-oxabicyclo<4.3.0>non-3-ene 
• 439919-46-7 cis-1,6-dihydroxymethyl-3-cyclohexene 
• 260259-08-3 (3ar,7ac)-octahydro-isobenzofuran-5c,6c-diol 
• 259670-51-4 meso-3,4-dibenzoyloxy-8-oxabicyclo[4.3.0]nonane 
• 935-79-5 cis-1,2,3,6-tetrahydrophthalic anhydride 
• 259670-55-8 C₂₂H₂₂O₆ 

Relevant academic research and scientific papers

Application of oxidative desymmetrization of meso-tetrahydrofurans: Syntheses of functionalized chiral building blocks and of (-)-alloyohimbane

Oxidative desymmetrization of oxygen functionalized mesotetrahydrofurans was successfully achieved (up to 87% ee) through (salen)manganese(III) catalyzed enantiotopic selective C-H oxidation. The enantioselective synthesis of (-)-alloyohimbane (12) has also been achieved in a short step by using oxidative desymmetrization of meso-tetrahydrofuran as the key step.