2597-39-9Relevant academic research and scientific papers
Homolytic decomposition of tertiary organochromium(III) complexes and evidence for their decomposition via reactions with aliphatic free radicals. A pulse radiolysis study
Mulac, William A.,Cohen, Haim,Meyerstein, Dan
, p. 4016 - 4020 (1982)
The rates of homolytic decomposition of Cr-C(CH3)2OH2+-, Cr-C(CH3)2CO2H2+, and Cr-C(CH3)2CN2+ are 0.15 s-1, 4 s-1, and 104 -6 s-1, respectively. The reaction of some aliphatic free radicals,·R with CrIII-R complexes is very fast, K3 ≥ 108 M-1 S-1. The rate of reaction of Cr2+(aq) with H2O2 is k16 = (3.7 ±0.7) × 104 M-1 s-1 in good accord with the literature value. These results are discussed in detail.
