Inorganic Chemistry p. 4016 - 4020 (1982)
Update date:2022-08-04
Topics:
Mulac, William A.
Cohen, Haim
Meyerstein, Dan
The rates of homolytic decomposition of Cr-C(CH3)2OH2+-, Cr-C(CH3)2CO2H2+, and Cr-C(CH3)2CN2+ are 0.15 s-1, 4 s-1, and 104 < k < 10-6 s-1, respectively. The reaction of some aliphatic free radicals,·R with CrIII-R complexes is very fast, K3 ≥ 108 M-1 S-1. The rate of reaction of Cr2+(aq) with H2O2 is k16 = (3.7 ±0.7) × 104 M-1 s-1 in good accord with the literature value. These results are discussed in detail.
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