25974-85-0

Upstream product

• 128797-16-0 (4aS,8aR)-4-Oxo-decahydro-naphthalene-1-carboxylic acid (1R,2S,5R)-2-isopropyl-5-methyl-cyclohexyl ester 
• 128797-14-8 (4aS,8aR)-4-Oxo-decahydro-naphthalene-1-carboxylic acid (1R,2S,5R)-5-methyl-2-(1-methyl-1-naphthalen-2-yl-ethyl)-cyclohexyl ester 
• 128797-15-9 4-Oxo-decahydro-naphthalene-1-carboxylic acid (1R,2S,5R)-2-[1-(4-methoxy-phenyl)-1-methyl-ethyl]-5-methyl-cyclohexyl ester 
• 128797-13-7 (4aR,8aS)-4-Oxo-decahydro-naphthalene-1-carboxylic acid (1R,2S,5R)-5-methyl-2-(1-methyl-1-phenyl-ethyl)-cyclohexyl ester 
• 128797-13-7 (4aS,8aR)-4-Oxo-decahydro-naphthalene-1-carboxylic acid (1R,2S,5R)-5-methyl-2-(1-methyl-1-phenyl-ethyl)-cyclohexyl ester 

Relevant academic research and scientific papers

Asymmetric Two-Fold Michael Reaction. Synthesis of Optically Active 4-Substituted 1-Decalones from Trimethylsilyl Enol Ether of 1-Acetylcyclohexene

Acrylates having a chiral auxiliary react with the trimethylsilyl enol ether of 1-acetylcyclohexene in the presence of Et2AlCl to give 4-substituted 1-decalones with 0-70percent diastereoselectivity.The absolute stereostructure of the decalones have been determined by applying the exciton chirality method to the dibenzoate derivative.