2599-84-0

Basic information

• Product Name: 2-[2-(Heptafluoropropoxy)-1,1,2,3,3,3-hexafluoropropoxy]-1,1,2,3,3,3-hexafluoropropyl(trifluorovinyl) ether
• Synonyms: 2-[2-(Heptafluoropropoxy)-1,1,2,3,3,3-hexafluoropropoxy]-1,1,2,3,3,3-hexafluoropropyl(trifluorovinyl) ether
• CAS NO: 2599-84-0
• Molecular Formula: C₁₁F₂₂O₃
• Molecular Weight: 598.08
• Mol File: 2599-84-0.mol
• Article Data: 1

Chemical Properties

• Boiling Point: 233.4±40.0 °C(Predicted)
• Appearance: /
• Density: 1.745±0.06 g/cm3(Predicted)
• CAS DataBase Reference: 2-[2-(Heptafluoropropoxy)-1,1,2,3,3,3-hexafluoropropoxy]-1,1,2,3,3,3-hexafluoropropyl(trifluorovinyl) ether(CAS DataBase Reference)
• NIST Chemistry Reference: 2-[2-(Heptafluoropropoxy)-1,1,2,3,3,3-hexafluoropropoxy]-1,1,2,3,3,3-hexafluoropropyl(trifluorovinyl) ether(2599-84-0)
• EPA Substance Registry System: 2-[2-(Heptafluoropropoxy)-1,1,2,3,3,3-hexafluoropropoxy]-1,1,2,3,3,3-hexafluoropropyl(trifluorovinyl) ether(2599-84-0)

Safety Data

• Hazardous Substances Data: 2599-84-0(Hazardous Substances Data)

Upstream product

• 22480-64-4 4-bromophenyllithium 
• 79851-30-2 2,3,3,3-Tetrafluoro-2-[1,1,2,3,3,3-hexafluoro-2-(1,1,2,3,3,3-hexafluoro-2-heptafluoropropyloxy-propoxy)-propoxy]-propionic acid ethyl ester 
• 67727-69-9 2,3,3,3-Tetrafluoro-2-[1,1,2,3,3,3-hexafluoro-2-(1,1,2,3,3,3-hexafluoro-2-heptafluoropropyloxy-propoxy)-propoxy]-1-phenyl-propan-1-one 
• 2388-07-0 lithium ethoxide 
• 106-37-6 1.4-dibromobenzene 

Relevant articles and documents

FLUORO-KETONES. V REACTIONS OF ALKYL AND ARYLLITHIUM COMPOUNDS WITH PERFLUOROALKYLETHER ESTERS

n-Butyllithium and a variety of aryllithium compounds have been shown to react with a perfluoroalkylether ester (RfORfCO2R) at -78 deg C to produce perfluoroalkylether ketones.In the absence of competing reactions, which may be due to additional reactive groups on the ester, high yields of ketones can be prepared.Steric hindrance adjacent to the carbonyl group has an important effect on rates of reactions.Low reaction temperature (-78 deg C) is an important factor when secondary esters are used.At higher reaction temperatures (> -30 deg C), the secondary esters produce decreased yields of ketone due to the instability of the intermediate lithium salt of the hemiketal which decomposes to an aryl ester and a perfluorinated olefin.