26049-09-2Relevant academic research and scientific papers
Methyltrioxorhenium-Catalyzed Oxidation of Secondary and Primary Amines with Hydrogen Peroxide
Yamazaki, Shigekazu
, p. 877 - 883 (1997)
The methyltrioxorhenium-catalyzed oxidation of secondary amines and primary amines with hydrogen peroxide has been carried out. The oxidation of secondary amines afforded nitrones in good-to-excellent yield. Benzylamines were selectively oxidized to oximes, while general primary alkylamines possessing the α-C -H bond gave mixtures of oximes, nitroso dimers, and azoxy compounds.
Direct transformation of benzilic amines to carbonyls using polyacrylamide-bound tungstate under phase-transfer catalysis conditions
Hamamoto, Hiromi,Suzuki, Yachiyo,Takahashi, Hideyo,Ikegami, Shiro
, p. 4239 - 4242 (2008/02/08)
A recyclable catalytic system under heterogeneous phase-transfer catalysis conditions was designed by using polyacrylamide-bound tungstate. A convenient method for the oxidative direct transformation of benzilic amines to carbonyls with hydrogen peroxide was then developed.
OXIDATION OF PRIMARY ALIPHATIC AMINES WITH SODIUM PERBORATE
Zajac, Walter W.,Darcy, Michael G.,Subong, Amador P.,Buzby, John H.
, p. 6495 - 6496 (2007/10/02)
A biphasic system of ethyl acetate and water containing sodium perborate, sodium bicarbonate and N,N,N',N'-tetraacetylethylenediamine oxidizes primary aliphatic amines to aliphatic C-nitroso compounds in good to excellent yields.
Oxidation of Primary Aliphatic Amines to C-Nitroso Dimers
Zajac, Walter W.,Walters, Thomas R.,Woods, James M.
, p. 808 - 810 (2007/10/02)
A biphasic system of ethyl acetate or dichloromethane and water containing sodium percarbonate (Na2CO3*3/2H2O2), sodium hydrogen carbonate and N,N,N',N'-tetraacetylethylenediamine oxidizes primary aliphatic amines to aliphatic C-nitroso dimers in most cases in good to excellent yields.
