Bulletin of the Chemical Society of Japan p. 877 - 883 (1997)
Update date:2022-08-04
Topics:
Yamazaki, Shigekazu
The methyltrioxorhenium-catalyzed oxidation of secondary amines and primary amines with hydrogen peroxide has been carried out. The oxidation of secondary amines afforded nitrones in good-to-excellent yield. Benzylamines were selectively oxidized to oximes, while general primary alkylamines possessing the α-C -H bond gave mixtures of oximes, nitroso dimers, and azoxy compounds.
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