26057-16-9

Basic information

• Product Name: Phosphoric acid, diethyl 2-methoxy-4-(2-propenyl)phenyl ester
• CAS NO: 26057-16-9
• Molecular Formula: C14H21O5P
• Molecular Weight: 300.292
• Mol File: 26057-16-9.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: Phosphoric acid, diethyl 2-methoxy-4-(2-propenyl)phenyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: Phosphoric acid, diethyl 2-methoxy-4-(2-propenyl)phenyl ester(26057-16-9)
• EPA Substance Registry System: Phosphoric acid, diethyl 2-methoxy-4-(2-propenyl)phenyl ester(26057-16-9)

Safety Data

• Hazardous Substances Data: 26057-16-9(Hazardous Substances Data)

Upstream product

• 97-53-0 4-allylguaiacol 
• 762-04-9 Diethyl phosphonate 
• 762-04-9 phosphonic acid diethyl ester 

Downstream Products

• 24743-14-4 1-allyl-3-methoxybenzene 
• 1446-24-8 3-allylphenol 
• 549532-78-7 3-allylphenyl acetate 

Relevant articles and documents

The reduction of aryl diethyl phosphate esters with lithium di-tert-butylbiphenylide radical anion: Aromatic hydrocarbons via the deoxygenation of phenols

The reduction of aryl diethyl phosphate esters by lithium 4,4′-di-tert-butylbiphenylide (LiDTBB) in THF at 0 °C is described. The reactions can be carried out either stoichiometrically (3.0 equiv LiDTBB) or with only a catalytic amount of DTBB (0.25 equiv) in the presence of lithium (2.1-3.0 equiv) and the phosphate. Products are separated from DTBB by solubility differences, by acid/base vs. neutral extraction, or by flash chromatography.