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Arsine, tris(2,4,6-trimethylphenyl)-, also known as tris(2,4,6-trimethylphenyl)arsine, is a chemical compound with the molecular formula C21H27As. It is an organoarsenic compound characterized by the presence of an arsenic atom bonded to three 2,4,6-trimethylphenyl groups. Arsine, tris(2,4,6-trimethylphenyl)- is a colorless, crystalline solid with a melting point of approximately 150°C. Tris(2,4,6-trimethylphenyl)arsine is primarily used as a ligand in coordination chemistry, particularly in the formation of metal complexes. It is also known for its potential applications in materials science and as a precursor in the synthesis of other organoarsenic compounds. Due to its arsenic content, it is considered toxic and requires proper handling and disposal.

2606-64-6

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2606-64-6 Usage

Check Digit Verification of cas no

The CAS Registry Mumber 2606-64-6 includes 7 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 4 digits, 2,6,0 and 6 respectively; the second part has 2 digits, 6 and 4 respectively.
Calculate Digit Verification of CAS Registry Number 2606-64:
(6*2)+(5*6)+(4*0)+(3*6)+(2*6)+(1*4)=76
76 % 10 = 6
So 2606-64-6 is a valid CAS Registry Number.

2606-64-6SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 15, 2017

Revision Date: Aug 15, 2017

1.Identification

1.1 GHS Product identifier

Product name tris(2,4,6-trimethylphenyl)arsane

1.2 Other means of identification

Product number -
Other names trimesitylarsine

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:2606-64-6 SDS

2606-64-6Relevant academic research and scientific papers

Tertiary arsine ligands for the Stille coupling reaction

Chishiro, Akane,Imoto, Hiroaki,Inaba, Ryoto,Konishi, Masafumi,Naka, Kensuke,Yumura, Takashi

, p. 95 - 103 (2021/12/27)

The Stille coupling reaction is one of the most important coupling reactions. It is well known that the triphenylarsine ligand can accelerate the reaction rate of Stille coupling. However, other arsine ligands have never been investigated for the Stille c

Fundamental Study on Arsenic(III) Halides (AsX3; X = Br, I) toward the Construction of C3-Symmetrical Monodentate Arsenic Ligands

Tanaka, Susumu,Konishi, Masafumi,Imoto, Hiroaki,Nakamura, Yuma,Ishida, Masatoshi,Furuta, Hiroyuki,Naka, Kensuke

supporting information, p. 9587 - 9593 (2020/07/02)

Arsenic ligands have attracted considerable attention in coordination chemistry. Arsenic(III) halides are the most important starting materials in the preparation of monodentate arsenic ligands. In this work, we optimized the synthetic methodologies of arsenic(III) halides (AsX3; X = Br, I) and examined the difference of their physical properties such as solubility to organic solvent and reactivity to nucleophiles. In addition, a wide variety of monodentate arsenic ligands were prepared with the obtained AsX3. Finally, the obtained monodentate arsenic ligands were utilized for copper-free Sonogashira cross-coupling reaction in the reaction system with porphyrin. The results showed that monodentate arsenic ligands have higher catalytic activity compared with triphenylphosphine because of the difference of the electronic features of lone pairs between arsenic and phosphorus atoms.

Fourier-transform Raman and infrared spectra and normal coordinate analysis of the triphenyl compounds and their methyl-, methoxy- and fluoro-substituted derivatives of arsenic, antimony and bismuth

Ludwig,Dolny,Goetze

, p. 2363 - 2372 (2007/10/03)

The Fourier transform (FT)-Raman and infrared (IR) spectra of triphenyl-, perdeuterated triphenyl-, tris(2-methylphenyl)-, tris(3-methylphenyl)-, tris(2,4,6-trimethylphenyl)-, tris(2-methoxyphenyl)-, tris(3-methoxyphenyl)-, tris(3-fluorophenyl)- and tris(

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