260780-10-7

Upstream product

• 39497-64-8 3,3-dimethyl-2-methylenebutan-1-ol 
• 100-39-0 benzyl bromide 
• 260403-52-9 methyl 2-O-(2-tert-butyl-2-propenyl)-3,4-O-isopropylidene-β-L-arabinofuranoside 
• 151557-52-7 2-tert-butyl-2-propen-1-ol p-toluenesulfonate 
• 260403-53-0 methyl 2-O-(2-tert-butyl-2-propenyl)-β-L-arabinopyranoside 
• 260403-54-1 methyl 3,4-di-O-benzyl-2-O-(2-tert-butyl-2-propenyl)-β-L-arabinopyranoside 

Relevant academic research and scientific papers

Stereoselective Template-directed C-Glycosidation. Synthesis of Bicyclic Ketooxetanes via Intramolecular Cyclization Reactions of (2-Pyridylthio)glycosidic Silyl Enol Ethers

Bicyclic ketooxetanes 5a, 5b and 8 are formed with excellent stereoselectivity on treatment of (2-pyridylthio)glycosidic silyl enol ethers 1a, 1b and 2 with silver(I) trifluoromethanesulfonate.

Template-directed intramolecular c-glycosidation. Cation- mediated synthesis of ketooxetanes from thioglycosides

Bicyclic ketooxetanes may be assembled using cation-mediated cyclisation reactions of thioglycosides possessing silyl enol ether-containing side-chains.