260782-77-2

Upstream product

• 2633-64-9 4-vinylbenzenesulfonamide 
• 260782-75-0 (E,E,E)-1,14-dibromo-N,N'-bis[(2,4,6-triisopropylphenyl)sulfonyl]-5,10-diazatetradeca-2,7,12-triene 
• 2695-37-6 sodium 4-styrenesulfonate 
• 2633-67-2 4-vinylbenzenesulfonyl chloride 
• 260782-76-1 (E)-N,N'-bis[(2,4,6-triisopropylphenyl)sulfonyl]-2-butene-1,4-diamine 
• 105536-22-9 2,4,6-triisopropylbenzene sulfonamide 

Relevant academic research and scientific papers

Preparation of nitrogen-containing 15-membered triolefinic macrocycles: (E,E,E)-1,6,11-tris(arylsulfonyl)-1,6,11-triazacyclopentadeca-3,8,13-trienes

Three routes to (E,E,E)-1,6,11-tris(arylsulfonyl)-1,6,11-triazacyclopentadeca-3,8,13-trienes are described. Optimization of the preparation of key intermediates has opened the way to efficient synthesis of a broad variety of 15-membered, nitrogen-containing triolefinic macrocycles.

Palladium(0) complexes of a 15-membered macrocyclic triolefin as a recoverable catalyst - Monomer- and polystyrene-anchored versions

Preparation of the 15-membered cycle (E,E,E)-1,6,11-tris[(2,4,6- triisopropylphenyl)sulfonyl]-1,6,11-triazacyclopentadeca-3,8,13-triene (8) is reported. This cyclic triolefin forms a stable Pd°complex 9 which catalyzes several cross-coupling reactions and