26092-49-9Relevant academic research and scientific papers
Synthesis of Symmetric Bridged Bis-Pyrazolone Based Metal Complex Acid Dyes and their Applications on Leather
Ayaz, Muhammad,Ayaz, Muhammad,Ali, Farman,Saeed, Aamer,Khurshid, Asma,Shabir, Ghulam,Ahmad, Tanveer,Kazmi, Syed Asad Raza,Khan, Hassan Ali
, p. 1181 - 1193 (2018)
Our present investigation aims at the synthesis and application of new, symmetric bridged bis-pyrazolone based acid dyes. The bis-pyrazolone compounds were accomplished from bis- hydrazine of 4,4′-Diaminostilbene-2,2′-disulfonic acid and ethyl acetoacetate. The bis-pyrazolones have been coupled with diazonium salts of o-hydroxyl aromatic amines which resulted in ligand dyes. The intermediate ligand dyes were treated with 3d transition metals to achieve the targeted metal complex acid dyes. The structures of investigated compounds were confirmed with the help of spectroscopic techniques. Dyes were applied on leather and their application parameters including their light fastness, wash fastness and rubbing fastness were determined. [Figure not available: see fulltext.].
Synthesis and Serviceability of New Symmetric Bis-pyrazolone Metal Complex Acid Dyes
Ayaz,Ali,Saeed,Abbas,Khan,Shabir,Saleem,Raza Kazmi,Khanzada
, p. 2498 - 2503 (2020/02/25)
Synthesis of new symmetric bis-pyrazolone acid dye and its 3d transition metal complexes is studied. Bis-pyrazolone is synthesized from (E)-6,6’-(ethene-1,2-diyl)bis(3-hydrazinylbenzenesulfonic acid) and ethyl ace-toacetate. The synthesized bis-pyrazolone is coupled with diazonium salt of 4-sulpho-2-aminophenol in alkaline medium targeting bis-pyrazolone ligand acid dye. Various metal complexes are obtained by treating a methanolic solution of metal salts with ligand acid dye in basic media. Structures of the synthesized ligand dye and its metal complexes are confirmed by UV-Vis, FTIR, and NMR spectra. The ligand acid dye and metal complex dyes demonstrate absorption in UV-Vis in the range of 400–600 nm. Ligand acid dye and its metal complexes demonstrate good to high value of light speed, washing fastness and rubbing fastness on leather.
Therapeutic and diagnostic ligand systems comprising transport molecule binding properties and medicaments containing the same
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, (2008/06/13)
The invention relates to transport molecule binding ligand compounds which comprise a therapeutically and/or diagnostically active substance and a carrier molecule-affine substance with a high association constant to the carrier molecule. The invention also relates to medicaments containing these ligand compounds and to diagnostic kits.
