260976-39-4

Upstream product

• 117252-95-6 2-(trimethylsilyl)ethyl β-D-galactopyranoside 
• 103082-76-4 2'-trimethylsilylethanyl 2,3,4,6-tetra-O-acetyl-β-D-galactopyranoside 
• 155135-78-7 2-(trimethylsilyl)ethyl 2,3-di-O-benzyl-4,6-O-benzylidene-β-D-galactopyranoside 
• 117252-96-7 2-(trimethylsilyl)ethyl 4,6-di-O-benzylidene-β-D-galactopyranoside 
• 98-59-9 p-toluenesulfonyl chloride 
• 191924-41-1 2-(trimethylsilyl)ethyl 2,3-di-O-benzyl-β-D-galactopyranoside 

Downstream Products

• 260976-40-7 2-(trimethylsilyl)ethyl 6-azido-2,3-di-O-benzyl-6-deoxy-β-D-galactopyranoside 
• 425623-85-4 2-(trimethylsilyl)ethyl 2,3-di-O-benzyl-6-deoxy-β-D-galactopyranoside 
• 88773-22-2 4-azido-2,3-di-O-benzyl-4,6-dideoxy-β-D-glucopyranosyl trichloroacetimidate 
• 425623-87-6 2-(trimethylsilyl)ethyl 4-azido-2,3-di-O-benzyl-4,6-dideoxy-β-D-glucopyranoside 
• 425623-86-5 2-(trimethylsilyl)ethyl 2,3-di-O-benzyl-6-deoxy-4-O-(p-tolylsulfonyl)-β-D-galactopyranoside 
• 425623-88-7 4-azido-2,3-di-O-benzyl-4,6-dideoxy-α-D-glucopyranosyl dibenzyl phosphateate 
• 260976-41-8 2-(trimethylsilyl)ethyl 6-azido-2,3,4-tri-O-benzyl-6-deoxy-β-D-galactopyranoside 
• 260976-43-0 2-(trimethylsilyl)ethyl (6-azido-2,3,4-tri-O-benzyl-6-deoxy-α-D-galactopyranosyl)-(1->4)-2,3,6-tri-O-benzoyl-β-D-galactopyranoside 

Relevant academic research and scientific papers

Biosynthetic studies on the α-glucosidase inhibitor acarbose: The chemical synthesis of dTDP-4-amino-4,6-dideoxy-α-D-glucose

To study the biosynthesis of the pseudotetrasaccharide acarbose, dTDP-4-amino-4,6-dideoxy-α-D-glucose (3) was prepared from galactose in 16 steps. After initial protecting-group manipulations, the 6-position of galactose was deoxygenated by hydride displa

Synthesis of selected aminodeoxy analogues of galabiose and globotriose

Six aminodeoxy 2-(trimethylsilyl)ethyl (Me3SiEt) glycoside analogues of galabiose (4'- and 6'-aminodeoxy) and globotriose (6''-, 4''-, 2''-, and 6'-aminodeoxy) were synthesized by glycosylation of protected Me3SiEt galactoside and lactoside acceptors with azido-substituted monosaccharide donors, followed by reduction of the azido groups and removal of the protecting groups. Copyright (C) 1999 Elsevier Science Ltd.