88773-22-2

Upstream product

• 545-06-2 trichloroacetonitrile 
• 117252-96-7 2-(trimethylsilyl)ethyl 4,6-di-O-benzylidene-β-D-galactopyranoside 
• 425623-86-5 2-(trimethylsilyl)ethyl 2,3-di-O-benzyl-6-deoxy-4-O-(p-tolylsulfonyl)-β-D-galactopyranoside 
• 425623-87-6 2-(trimethylsilyl)ethyl 4-azido-2,3-di-O-benzyl-4,6-dideoxy-β-D-glucopyranoside 
• 425623-85-4 2-(trimethylsilyl)ethyl 2,3-di-O-benzyl-6-deoxy-β-D-galactopyranoside 
• 103082-76-4 2'-trimethylsilylethanyl 2,3,4,6-tetra-O-acetyl-β-D-galactopyranoside 
• 117252-95-6 2-(trimethylsilyl)ethyl β-D-galactopyranoside 
• 260976-39-4 2-(trimethylsilyl)ethyl 2,3-di-O-benzyl-6-O-p-toluenesulfonyl-β-D-galactopyranoside 
• 191924-41-1 2-(trimethylsilyl)ethyl 2,3-di-O-benzyl-β-D-galactopyranoside 
• 155135-78-7 2-(trimethylsilyl)ethyl 2,3-di-O-benzyl-4,6-O-benzylidene-β-D-galactopyranoside 

Downstream Products

• 425623-88-7 4-azido-2,3-di-O-benzyl-4,6-dideoxy-α-D-glucopyranosyl dibenzyl phosphateate 

Relevant academic research and scientific papers

Biosynthetic studies on the α-glucosidase inhibitor acarbose: The chemical synthesis of dTDP-4-amino-4,6-dideoxy-α-D-glucose

To study the biosynthesis of the pseudotetrasaccharide acarbose, dTDP-4-amino-4,6-dideoxy-α-D-glucose (3) was prepared from galactose in 16 steps. After initial protecting-group manipulations, the 6-position of galactose was deoxygenated by hydride displa