261509-63-1

Basic information

• Product Name: methyl (Z)-2-(N-Cbz)amino-5-triphenylphosphinopent-2-enoate
• Synonyms: methyl (Z)-2-(N-Cbz)amino-5-triphenylphosphinopent-2-enoate
• CAS NO: 261509-63-1
• Molecular Weight: 538.583
• Mol File: 261509-63-1.mol

Chemical Properties

• CAS DataBase Reference: methyl (Z)-2-(N-Cbz)amino-5-triphenylphosphinopent-2-enoate(CAS DataBase Reference)
• NIST Chemistry Reference: methyl (Z)-2-(N-Cbz)amino-5-triphenylphosphinopent-2-enoate(261509-63-1)
• EPA Substance Registry System: methyl (Z)-2-(N-Cbz)amino-5-triphenylphosphinopent-2-enoate(261509-63-1)

Safety Data

• Hazardous Substances Data: 261509-63-1(Hazardous Substances Data)

Upstream product

• 261509-61-9 methyl (Z)-2-(N-Cbz)amino-5-tosyloxypent-2-enoate 
• 261509-60-8 methyl (Z)-2-(N-Cbz)amino-5-mesyloxypent-2-enoate 
• 139125-35-2 methyl (Z)-2-(N-Cbz)amino-5-hydroxypent-2-enoate 
• 603-35-0 triphenylphosphine 
• 261509-62-0 methyl (Z)-2-(N-Cbz)amino-5-azidopent-2-enoate 
• 130680-59-0 Cbz-ΔGlu-OMe 

Downstream Products

• 261509-67-5 Boc-1-Tyr(MOM)-(Z)-ΔArg(Boc2)-OMe 
• 261509-66-4 Boc-1-Tyr(MOM)-(Z)-ΔOrn(Cbz)-OMe 
• 114684-70-7 Cbz-(Z)-Δ-Orn(Cbz)-OMe 
• 121592-48-1 Cbz-(Z)-ΔOrn(Cbz)-OH 
• 114684-74-1 Cbz-(Z)-ΔOrn(Cbz)NCA 
• 130680-67-0 Cbz-(Z)-Δ-Orn(Boc)-OMe 

Relevant articles and documents

Convenient synthesis and conversion of a (Z)-α,β-didehydroornithine derivative to α,β-didehydrokyotorphin

Hydrogenolysis of the azido group of methyl (Z)-2-(N-Cbz)amino-5- azidopent-2-enoate, derived by selective reduction and azidation of the side chain carboxyl group of N-protected (Z)ΔGlu-OMe, gave (Z)-α,β- didehydroornithine derivative (7). The formed 7 was further converted to the basic (Z)-α,β-didehydroarginine and the acid containing (Z)-α,β- didehydrokyotorphin.