139125-35-2

Basic information

• Product Name: 2-Pentenoic acid, 5-hydroxy-2-[[(phenylmethoxy)carbonyl]amino]-, methyl ester, (Z)-
• CAS NO: 139125-35-2
• Molecular Formula: C14H17NO5
• Molecular Weight: 279.293
• Mol File: 139125-35-2.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: 2-Pentenoic acid, 5-hydroxy-2-[[(phenylmethoxy)carbonyl]amino]-, methyl ester, (Z)-(CAS DataBase Reference)
• NIST Chemistry Reference: 2-Pentenoic acid, 5-hydroxy-2-[[(phenylmethoxy)carbonyl]amino]-, methyl ester, (Z)-(139125-35-2)
• EPA Substance Registry System: 2-Pentenoic acid, 5-hydroxy-2-[[(phenylmethoxy)carbonyl]amino]-, methyl ester, (Z)-(139125-35-2)

Safety Data

• Hazardous Substances Data: 139125-35-2(Hazardous Substances Data)

Upstream product

• 130680-59-0 Cbz-ΔGlu-OMe 
• 96658-32-1 Cbz-ΔGlu(OMe)-OH 
• 67-56-1 methanol 
• 139125-22-7 2-(N-Cbz-amino)-5-hydroxy-2-pentenoic acid 

Downstream Products

• 261509-67-5 Boc-1-Tyr(MOM)-(Z)-ΔArg(Boc2)-OMe 
• 261509-66-4 Boc-1-Tyr(MOM)-(Z)-ΔOrn(Cbz)-OMe 
• 261509-63-1 methyl (Z)-2-(N-Cbz)amino-5-triphenylphosphinopent-2-enoate 
• 261509-62-0 methyl (Z)-2-(N-Cbz)amino-5-azidopent-2-enoate 
• 114684-70-7 Cbz-(Z)-Δ-Orn(Cbz)-OMe 
• 121592-48-1 Cbz-(Z)-ΔOrn(Cbz)-OH 
• 114684-74-1 Cbz-(Z)-ΔOrn(Cbz)NCA 
• 130680-67-0 Cbz-(Z)-Δ-Orn(Boc)-OMe 
• 261509-61-9 methyl (Z)-2-(N-Cbz)amino-5-tosyloxypent-2-enoate 
• 261509-60-8 methyl (Z)-2-(N-Cbz)amino-5-mesyloxypent-2-enoate 

Relevant articles and documents

Convenient synthesis and conversion of a (Z)-α,β-didehydroornithine derivative to α,β-didehydrokyotorphin

Hydrogenolysis of the azido group of methyl (Z)-2-(N-Cbz)amino-5- azidopent-2-enoate, derived by selective reduction and azidation of the side chain carboxyl group of N-protected (Z)ΔGlu-OMe, gave (Z)-α,β- didehydroornithine derivative (7). The formed 7 was further converted to the basic (Z)-α,β-didehydroarginine and the acid containing (Z)-α,β- didehydrokyotorphin.