26154-35-8Relevant academic research and scientific papers
CORRELATED INTERNAL ROTATION IN BIS(2,6-DICHLORO-9-TRIPTYCYL)METHANE. TO WHAT EXTENT CAN PHASE ISOMERS BE SEPARATED AND IDENTIFIED?
Kawada, Yuzo,Okamoto, Yoshio,Iwamura, Hiizu
, p. 5359 - 5362 (1983)
The title compound was separated by HPLC into the stereoisomers (one meso and four racemic compounds) due to the asymmetric bridgehead carbons and the correlated internal rotation.Optical resolution of the racemic compounds was performed by HPLC using a chiral support.
Bimolecular formation of radicals by hydrogen transfer. 14: The uncatalyzed transfer hydrogenation of α-methylstyrene by 2,6-disubstituted 9,10-dihydroanthracenes
Keller, Friedrich,Ruechardt, Christoph
, p. 642 - 648 (2011/10/09)
2,6-Dimethoxy- (4a), 2,6-bis(dimethylamino)- (4b), 2,6-dichloro- (4c) and 2,6-dimethoxycarbonyl-9,10-dihydroanthracene (4d) were prepared by conventional methods and used as hydrogen transfer donors to α-methylstyrene (5) between 290-350°C. The mechanism
