26157-49-3

Basic information

• Product Name: 2-(1'-Cyclohexenyl)-2-methyl-acetonitrile
• Synonyms: 2-(1'-Cyclohexenyl)-2-methyl-acetonitrile
• CAS NO: 26157-49-3
• Molecular Weight: 135.209
• Mol File: 26157-49-3.mol
• Article Data: 5

Chemical Properties

• CAS DataBase Reference: 2-(1'-Cyclohexenyl)-2-methyl-acetonitrile(CAS DataBase Reference)
• NIST Chemistry Reference: 2-(1'-Cyclohexenyl)-2-methyl-acetonitrile(26157-49-3)
• EPA Substance Registry System: 2-(1'-Cyclohexenyl)-2-methyl-acetonitrile(26157-49-3)

Safety Data

• Hazardous Substances Data: 26157-49-3(Hazardous Substances Data)

Upstream product

• 7677-24-9 trimethylsilyl cyanide 
• 90087-64-2 1-(1-nitroethyl)cyclohexene 
• 107466-02-4 Phosphoric acid cyano-cyclohex-1-enyl-methyl-methyl ester diethyl ester 
• 4354-73-8 2-(cyclohexylidene)malononitrile 
• 108-94-1 cyclohexanone 
• 932-66-1 1-cyclohexenyl methyl ketone 
• 35677-28-2 (R)-Cyano-cyclohex-1-enyl-methyl-acetic acid 
• 16933-89-4 3-methyl-2-oxo-1-aza-spiro[3.5]nonane-1-sulfonyl chloride 
• 69016-12-2 Methylcyclohexenylcyanoacetic acid methyl ester 

Downstream Products

• 1003-64-1 ethylidenecyclohexane 
• 90355-38-7 (-)-4-Cyano-4-(1'-cyclohexenyl)-4-methyl-butyric acid 
• 90355-38-7 (+)-4-Cyano-4-(1'-cyclohexenyl)-4-methyl-butyric acid 
• 90355-38-7 4-Cyano-4-(1'-cyclohexenyl)-4-methyl-butyric acid 
• 90355-19-4 4-Cyano-4-(1'-cyclohexenyl)-4-methyl-butyric acid ethylester 
• 61346-65-4 2-cyclohex-1-enyl-propionic acid ethyl ester 
• 2205-24-5 2-cyclohex-1-enyl-propionic acid 
• 53153-76-7 2-cyclohexylidenepropanenitrile 

Relevant articles and documents

Non-reductive decyanation reactions of disubstituted malononitrile derivatives promoted by NaHMDS

A new method for achieving the decyanation of disubstituted malononitrile derivatives without using reducing agents has been developed. Treatment of a six-membered malononitrile derivative with NaHMDS followed by methanol afforded the corresponding acetonitrile derivative in high yield. The present method was applicable to the decyanation reactions of a variety of malononitriles including four- and five-membered compounds as well as acyclic ones.

CYANOPHOSPHATE: AN EFFICIENT INTERMEDIATE FOR CONVERSION OF CARBONYL COMPOUNDS TO NITRILES

A novel and high yield conversion of saturated or unsaturated carbonyl compounds to nitriles via cyanophosphates by samarium diiodide in the presence of tert-butanol is described.

2,6-Piperidinediones, I: Synthesis of the Racemates and Enantiomers of 3,3-Disubstituted 2,6-Piperidinediones

The synthesis of the racemates and the enantiomers of the 3,3-disubstituted 2,6-piperidinediones 3a-3g is performed in three ways, depending on the C-3 substituents.The 3-cyclohexylpiperidinedione 3h is obtained as racemic and optically active compound by