261639-84-3Relevant academic research and scientific papers
Layered donor-acceptor-acceptor arrangement in complex of molecular tweezer based on dioxa[2.2]orthocyclophane
Kurebayashi, Hirotaka,Haino, Takeharu,Fukazawa, Yoshimasa
, p. 477 - 480 (2000)
Flexible molecular receptors having three aromatic chromophores can bind electron deficient π-system such as TCNQ and TCNB with both face-to-face and face-to-edge interactions. The receptors have tweezer-type conformations when a guest was trapped within their cavities. Sandwich-type donor-acceptor- acceptor (DAA) arrangement was realized in the crystalline supramolecular complex.
Intramolecular complex formation between flexible molecular tweezers and weak electron acceptor
Kurebayashi, Hirotaka,Fukazawa, Yoshimasa
, p. 849 - 864 (2007/10/03)
A flexible receptor having three aromatic chromophores can bind a weak electron acceptor which is linked covalently to the receptor with alkyl chain of an appropriate length. The receptor has tweezers type conformation when the acceptor was entrapped within the cavity. Sandwich type donnor-acceptor-acceptor arrangement was realized in solution.
