261713-62-6

Basic information

• Product Name: 1,3,4,5-tetra-O-benzyl-7-deoxy-6-O-(3-tert-butyldimethylsilyloxy-2,2-dimethylpropyl)-L-xylo-hept-6-en-2-ulose
• Synonyms: 1,3,4,5-tetra-O-benzyl-7-deoxy-6-O-(3-tert-butyldimethylsilyloxy-2,2-dimethylpropyl)-L-xylo-hept-6-en-2-ulose
• CAS NO: 261713-62-6
• Molecular Weight: 753.064
• Mol File: 261713-62-6.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: 1,3,4,5-tetra-O-benzyl-7-deoxy-6-O-(3-tert-butyldimethylsilyloxy-2,2-dimethylpropyl)-L-xylo-hept-6-en-2-ulose(CAS DataBase Reference)
• NIST Chemistry Reference: 1,3,4,5-tetra-O-benzyl-7-deoxy-6-O-(3-tert-butyldimethylsilyloxy-2,2-dimethylpropyl)-L-xylo-hept-6-en-2-ulose(261713-62-6)
• EPA Substance Registry System: 1,3,4,5-tetra-O-benzyl-7-deoxy-6-O-(3-tert-butyldimethylsilyloxy-2,2-dimethylpropyl)-L-xylo-hept-6-en-2-ulose(261713-62-6)

Safety Data

• Hazardous Substances Data: 261713-62-6(Hazardous Substances Data)

Upstream product

• 126-30-7 2,2-Dimethyl-1,3-propanediol 
• 261713-61-5 3,4,5,7-tetra-O-benzyl-1-deoxy-2-O-(3-tert-butyldimethylsilyloxy-2,2-dimethylpropyl)-D-gluco-hept-1-enitol 
• 261713-59-1 2,3,4,6-tetra-O-benzyl-5',5'-dimethylspiro[1,5-anhydro-D-glucitol-1,2'-[1,3]dioxane] 

Downstream Products

• 115250-38-9 (1S)-(1(OH),2,4/1,3)-2,3,4-Tri-O-benzyl-1-C-<(benzyloxy)methyl>-5-oxo-1,2,3,4-cyclohexanetetrol 

Relevant articles and documents

Facile ring transformation from gluconolactone to cyclitol derivative via spiro sugar ortho ester

(Formula presented) A short step preparation of cyclitol derivative 8 which is a versatile synthon for the synthesis of valiolamine and its related compounds is described. Key steps in this preparation are a novel enol ether formation from spiro sugar ortho esters with AIMe3 and an intramolecular Aldol condensation of alkyl enol ethers catalyzed by ZnCl2 in THF-H2O. With these reactions, gluconolactone derivative 1 was efficiently converted into 8 in short steps.