262-89-5Relevant articles and documents
Flow-Vacuum Pyrolysis of Polycyclic Compounds, 6. Pyrolysis of Dibenzo 8 Hydrocarbons
Banciu, Mircea D.,Stanescu, Michaela D.,Petride, Aurica,Parvulescu, Luminitza,Pop, Mircea
, p. 2513 - 2518 (2007/10/02)
The flow-vacuum pyrolysis of dibenzo 8 hydrocarbons 2, 3, 4, and 5 are studied at 1 Torr and in the temperature range between 400 and 650 deg C.The following new transformations have been observed: 24, 2-->5, 3-->5, 34, 3-->2, 5-->11, the last three presenting analogies in the 8 and/or benzo 8 series.A reaction mechanism is suggested. - Key Words: Dibenzo 8 hydrocarbons / Flow-vacuum pyrolysis
Reductive Coupling by Chromium(0) - (Bibenzyl)- and (Stilbene)tricarbonylchromium(0) Complexes by a One-Pot Reaction from Benzylic Halides
Wey, Hans G.,Butenschoen, Holger
, p. 93 - 99 (2007/10/02)
Reaction of Cr(CO)3(NH3)3 with benzylic mono-, di-, and trihalides leads to the formation of 1,2-diarylethanes, -ethenes, and diphenylethyne in satisfactory yields.Di(halomethyl)benzene derivatives yield product mixtures containing both reduction products and coupling products.With a higher excess in chromium(0), under otherwise unchanged reaction conditions, the corresponding (arene)tricarbonylchromium(0) complexes of the coupling products are formed in a one-pot reaction from the benzylic halides.