262290-94-8

Basic information

• Product Name: (3S)-3-[(1R)-4-Methylcyclohex-3-enyl]butanol dinitrobenzoate ester
• Synonyms: (3S)-3-[(1R)-4-Methylcyclohex-3-enyl]butanol dinitrobenzoate ester
• CAS NO: 262290-94-8
• Molecular Weight: 362.382
• Mol File: 262290-94-8.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (3S)-3-[(1R)-4-Methylcyclohex-3-enyl]butanol dinitrobenzoate ester(CAS DataBase Reference)
• NIST Chemistry Reference: (3S)-3-[(1R)-4-Methylcyclohex-3-enyl]butanol dinitrobenzoate ester(262290-94-8)
• EPA Substance Registry System: (3S)-3-[(1R)-4-Methylcyclohex-3-enyl]butanol dinitrobenzoate ester(262290-94-8)

Safety Data

• Hazardous Substances Data: 262290-94-8(Hazardous Substances Data)

Upstream product

• 15760-18-6 9-Hydroxy-methyl-Δ¹-p-menthen 
• 99-33-2 3,5-dinitrobenoyl chloride 

Downstream Products

• 262290-97-1 (1R)-5-[(1S)-3-Hydroxy-1,5-dimethylhexyl]-2-methylenecyclohexanol 
• 262290-96-0 (2S)-2-[(1R)-4-Methylcyclohex-3-enyl]-6-methylheptan-4-ol 
• 128300-30-1 (S)-3-((R)-4-methylcyclohex-3-en-1-yl)butanal 
• 26575-87-1 (+)-epijuvabione 
• 26091-09-8 (+)-Epitodomatuic acid 
• 26462-78-2 (R)-4-((S)-1,5-Dimethyl-3-oxo-hexyl)-cyclohex-1-enecarbaldehyde 
• 262290-92-6 (S)-3-((R)-4-Methyl-cyclohex-3-enyl)-butan-1-ol 

Relevant articles and documents

Baker's yeast mediated enantioselective synthesis of the bisabolene sesquiterpenes (+)-epijuvabione and (-)-juvabione

Fermenting baker's yeast converts the unsaturated aldehydes 7 and 11 into the saturated alcohols 8 and 12, respectively. The microbial saturation of the double bond proceeds in high chemical yields and the stereoselectivity of the reduction is strongly influenced by the E:Z ratio of the substrate. Enantiopure 8 and 12 are chiral building blocks for the synthesis of bisabolene sesquiterpenes and their usefulness is shown in the preparation of (+)-epijuvabione 1 and (-)-juvabione 3.