262605-30-1

Basic information

• Product Name: ethyl 2,3,4-tri-O-benzyl-6-O-(3-hydroxycarbonylpropanoyl)-1-thio-α-D-mannopyranoside
• Synonyms: ethyl 2,3,4-tri-O-benzyl-6-O-(3-hydroxycarbonylpropanoyl)-1-thio-α-D-mannopyranoside
• CAS NO: 262605-30-1
• Molecular Weight: 594.726
• Mol File: 262605-30-1.mol

Chemical Properties

• CAS DataBase Reference: ethyl 2,3,4-tri-O-benzyl-6-O-(3-hydroxycarbonylpropanoyl)-1-thio-α-D-mannopyranoside(CAS DataBase Reference)
• NIST Chemistry Reference: ethyl 2,3,4-tri-O-benzyl-6-O-(3-hydroxycarbonylpropanoyl)-1-thio-α-D-mannopyranoside(262605-30-1)
• EPA Substance Registry System: ethyl 2,3,4-tri-O-benzyl-6-O-(3-hydroxycarbonylpropanoyl)-1-thio-α-D-mannopyranoside(262605-30-1)

Safety Data

• Hazardous Substances Data: 262605-30-1(Hazardous Substances Data)

Upstream product

• 108-30-5 succinic acid anhydride 
• 39483-51-7 ethyl 2,3,4-tri-O-benzyl-1-thio-α-D-mannopyranoside 

Downstream Products

• 173725-98-9 ethyl 2,3,4-tri-O-benzyl-6-O-[3-(2-O-benzoyl-1,6-di-O-benzyl-α-D-glucopyranos-3-yloxy)-carbonylpropanoyl]-1-thio-α-D-mannopyranoside 
• 173725-99-0 benzyl O-(2,3,4-tri-O-benzyl-α-D-mannopyranosyl)(1->4)-2-O-benzoyl-6-O-benzyl-α-D-glucopyranoside-3,6-succinate 
• 173726-00-6 benzyl O-(2,3,4-tri-O-benzyl-β-D-mannopyranosyl)(1->4)-2-O-benzoyl-6-O-benzyl-α-D-glucopyranoside-3,6-succinate 
• 220009-62-1 benzyl 2,3-di-O-benzoyl-6-O-[4-(ethyl 2,3,4-tri-O-benzyl-1-thio-α-D-mannopyranosid-6-O-yl)-1,4-dioxobutyl]-α-D-galactopyranoside 

Relevant articles and documents

Synthesis of 4-O-D-mannopyranosyl-α-D-glucopyranosides by intramolecular glycosylation of 6-O-tethered mannosyl donors

A series of mannosyl donors linked via position 6 by a carbonate, oxalate, malonate, succinate, and phthalate tether, respectively, to position 3 of a glucoside and glucosamine acceptor afforded during intramolecular glycosylation, anomeric mixture of the corresponding disaccharides. The dependence of the diastereoselectivity on the glycosylation procedure, the solvent, and the blocking groups in comparison to an intermolecular mannosylation is studied. (C) 2000 Elsevier Science Ltd.