262605-52-7

Upstream product

• 85-44-9 phthalic anhydride 
• 152488-26-1 phenyl 2,3,4-tri-O-benzyl-1-thio-α-D-mannopyranoside 
• 262605-69-6 phenyl 2,3,4-tri-O-benzyl-6-O-triphenylmethyl-1-thio-α-D-mannopyranoside 
• 262605-68-5 phenyl 6-O-triphenylmethyl-1-thio-α-D-mannopyranoside 
• 2936-70-1 (2R,3S,4S,5S,6R)-2-Hydroxymethyl-6-phenylsulfanyl-tetrahydro-pyran-3,4,5-triol 
• 100-39-0 benzyl bromide 

Downstream Products

• 262605-60-7 phenyl 2,3,4-tri-O-benzyl-6-O-[(2-O-benzoyl-1,6-di-O-benzyl-α-D-glucopyranos-3-yloxy)-2-carbonylbenzoyl]-1-thio-α-D-mannopyranoside 
• 262605-65-2 benzyl O-(2,3,4-tri-O-benzyl-α-D-mannopyranosyl)(1->4)-2-O-benzoyl-6-O-benzyl-α-D-glucopyranoside-3,6-phthalate 
• 262605-66-3 benzyl O-(2,3,4-tri-O-benzyl-β-D-mannopyranosyl)(1->4)-2-O-benzoyl-6-O-benzyl-α-D-glucopyranoside-3,6-phthalate 

Relevant academic research and scientific papers

Stereoselective synthesis and properties of glycoazobenzene macrocycles through intramolecular glycosylation

An intramolecular glycosylation strategy was used to synthesize a series of new glycoazobenzene macrocycles with high α-selectivity and interesting chiroptical properties. The photoisomerization of an azobenzene template influences mainly the efficiency of the glycosylation.

Synthesis of 4-O-D-mannopyranosyl-α-D-glucopyranosides by intramolecular glycosylation of 6-O-tethered mannosyl donors

A series of mannosyl donors linked via position 6 by a carbonate, oxalate, malonate, succinate, and phthalate tether, respectively, to position 3 of a glucoside and glucosamine acceptor afforded during intramolecular glycosylation, anomeric mixture of the corresponding disaccharides. The dependence of the diastereoselectivity on the glycosylation procedure, the solvent, and the blocking groups in comparison to an intermolecular mannosylation is studied. (C) 2000 Elsevier Science Ltd.