262844-04-2

Upstream product

• 186581-53-3 diazomethane 
• 220820-69-9 (2S,4R,5S)-4-O-t-butyldimethylsilyl-1,2-O-isopropylidene-1,2,4,5-tetrahydroxy-5-phenylpentan-3-one 
• 100-52-7 benzaldehyde 
• 150811-51-1 (Z)-2-(tert-Butyldimethylsiloxy)-1-methoxy-1-(trimethylsiloxy)ethene 
• 262844-00-8 methyl (2R,3S)-2-O-t-butyldimethylsilyl-3-O-formyl-2,3-dihydroxy-3-phenylpropionate 

Downstream Products

• 122743-18-4 methyl (2R,3S)-2,3-dihydroxy-3-phenylpropanoate 

Relevant academic research and scientific papers

Lewis base activation of Lewis acids: Catalytic, enantioselective addition of glycolate-derived silyl ketene acetals to aldehydes

(Chemical Equation Presented) A catalytic system involving silicon tetrachloride and a chiral, Lewis basic bisphosphoramide catalyst is effective for the addition of glycolate-derived silyl ketene acetals to aldehydes. It was found that the sense of diast

Aldol reactions with erythrulose derivatives: Stereoselective synthesis of differentially protected syn-α,β-dihydroxy esters

Boron enolates of 1-O-silylated erythrulose 3,4-acetonides prepared with Brown's chloro-dicyclohexylborane/tertiary amine system have been shown to react with achiral aldehydes in a highly stereoselective way to yield a 1,2- syn/1,3-syn stereoisomer. Thro