26285-62-1 Usage
General Description
N,N-Dimethylaminomethyltributylstannane is a chemical compound with the molecular formula (CH3)2NCH2Sn(C4H9)3. It is a derivative of organotin compounds and is used as a reagent in organic synthesis and as a catalyst in various reactions. N,N-Dimethylaminomethyltributylstannane is known for its ability to facilitate carbon-carbon bond formation and for its role in promoting a wide range of carbon-carbon and carbon-heteroatom bond-forming reactions. It is also used in the synthesis of pharmaceuticals and agrochemicals. However, due to the toxic nature of organotin compounds, N,N-Dimethylaminomethyltributylstannane must be handled with care and proper safety precautions.
Check Digit Verification of cas no
The CAS Registry Mumber 26285-62-1 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 2,6,2,8 and 5 respectively; the second part has 2 digits, 6 and 2 respectively.
Calculate Digit Verification of CAS Registry Number 26285-62:
(7*2)+(6*6)+(5*2)+(4*8)+(3*5)+(2*6)+(1*2)=121
121 % 10 = 1
So 26285-62-1 is a valid CAS Registry Number.
InChI:InChI=1/3C4H9.C3H8N.Sn/c3*1-3-4-2;1-4(2)3;/h3*1,3-4H2,2H3;1H2,2-3H3;/rC15H35NSn/c1-6-9-12-17(13-10-7-2,14-11-8-3)15-16(4)5/h6-15H2,1-5H3
26285-62-1Relevant articles and documents
Preparation d'aminomethyltributyletains par stannylation de sels d'immonium au moyen du chlorure de tributylstannylmagnesium. Applications a la synthese de β-aminoalcools
Elissondo, Bernard,Verlhac, Jean-Baptiste,Quintard, Jean-Paul,Pereyre, Michel
, p. 267 - 276 (2007/10/02)
Tributylstannylmagnesium chloride reacts with immonium salts and gives nonsubstituted, α-substituted or α,α-disubstituted aminomethyltributyltins.The reaction, which can be extended to stannylation by tributylstannylalkalis, is not affected by the nature of the anionic part of the immonium salt.Transmetallation of aminomethyltributyltins with butyllithium, followed by condensation with carbonyl compounds, provides a regiospecific route to β-aminoalcohols.
