263768-77-0Relevant academic research and scientific papers
Birch reduction of aryldialkylphosphine-boranes
Stankevi?, Marek,Micha? Pietrusiewicz
supporting information; experimental part, p. 7093 - 7095 (2010/03/03)
Aryldialkylphosphine-boranes undergo facile Birch-type reduction to afford cyclohexadienyldialkylphosphine-boranes in high yields. Judicious choice of the metal and the reaction conditions allows for complete elimination of the undesired P-Ph bond cleavag
Synthesis and enantioselectivity of P-chiral phosphine ligands with alkynyl groups
Imamoto, Tsuneo,Saitoh, Youichi,Koide, Aya,Ogura, Tomokazu,Yoshida, Kazuhiro
, p. 8636 - 8639 (2008/09/18)
(Formula Presented) A range of asymmetric transformations are catalyzed by transition-metal complexes of the title ligands with excellent enantioselectivities. The ligands, which were applied successively in Rh-catalyzed hydrogenation and Rh- or Pd-cataly
