263898-70-0

Basic information

• Product Name: t-butyl 5-iodo-3-(p-methoxyphenyl)-4-methyl-2-pyrrolecarboxylate
• Synonyms: t-butyl 5-iodo-3-(p-methoxyphenyl)-4-methyl-2-pyrrolecarboxylate
• CAS NO: 263898-70-0
• Molecular Weight: 413.255
• Mol File: 263898-70-0.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: t-butyl 5-iodo-3-(p-methoxyphenyl)-4-methyl-2-pyrrolecarboxylate(CAS DataBase Reference)
• NIST Chemistry Reference: t-butyl 5-iodo-3-(p-methoxyphenyl)-4-methyl-2-pyrrolecarboxylate(263898-70-0)
• EPA Substance Registry System: t-butyl 5-iodo-3-(p-methoxyphenyl)-4-methyl-2-pyrrolecarboxylate(263898-70-0)

Safety Data

• Hazardous Substances Data: 263898-70-0(Hazardous Substances Data)

Upstream product

• 100780-39-0 t-Butyl 3-(p-methoxy-phenyl)-4-methylpyrrole-2-carboxylate 

Downstream Products

• 152796-97-9 4-(4-Methoxy-phenyl)-3-methyl-5-(toluene-4-sulfonyl)-1,5-dihydro-pyrrol-2-one 
• 263898-74-4 5-acetoxy-5-(t-butoxycarbonyl)-1,5-dihydro-4-(p-methoxyphenyl)-3-methyl-2H-pyrrol-2-one 

Relevant articles and documents

An efficient method to construct the A,B-rings component toward total syntheses of phycocyanobilin and its derivative as a photoprobe

Total syntheses of physocyanobilin and its derivative bearing a photoreactive group at the D-ring accomplished by developing a new and efficient method for the construction of A,B-rings component, which consists of the Wittig-type new coupling reaction of 4-(1-methoxyethyl or 1- tosylethyl)-3-methyl-5-tosyl-1,5-dihydro-2H-pyrrol-2-one and a 2-formyl pyrrole derivative in the presence of (n)Bu3P and a base, followed by reduction with aluminum amalgam and a subsequent acid or base treatment.