26452-86-8Relevant academic research and scientific papers
Generation and reactions of oxiranyllithiums by use of a flow microreactor system
Nagaki, Aiichiro,Takizawa, Eiji,Yoshida, Jun-Ichi
supporting information; experimental part, p. 14149 - 14158 (2011/02/25)
A flow microreactor system consisting of micromixers and microtubes provides an effective reactor for the generation and reactions of aryloxiranyllithiums without decomposition by virtue of short residence time and efficient temperature control. The depro
Stereospecific Substituted Alkene Synthesis by Organo Lithium Reductive Alkylation of Epoxides
Doris, Eric,Dechoux, Luc,Mioskowski, Charles
, p. 7943 - 7946 (2007/10/02)
Stereospecifically alkylated olefins were synthesized in good yields by reaction of various epoxides with organolithium reagents with concommitant introduction of the alkyl group.
Dienes, enynes and styrenes from Markovnikov vinylboranes via the Suzuki reaction
Rivera, Isaac,Soderquist, John A.
, p. 2311 - 2314 (2007/10/02)
The clean, efficient Pd-catalyzed cross coupling of vinyl, alkynyl and aryl bromides with Markovnikov vinylboranes gives 56-96% yields of the corresponding 1,3-dienes, 1-en-3-ynes and styrenes, with complete retention of configuration observed for the 1,3-dienes.
The reaction of iodine with vinyltrialkylborates derived from trialkylboranes and trisylhydrazones of methyl ketones. A new method for synthesis of 1,1-dialkylethenes
Avasthi, Kamlakar,Baba, Tsutomu,Suzuki, Akira
, p. 945 - 946 (2007/10/02)
1,1-Dialkylethenes are readily prepared in good yields from vinyltrialkylborates derived from trialkylboranes and trisylhydrazones of methyl ketones by treatment with iodine.
