76886-55-0

Upstream product

• 39085-59-1 trisylhydrazine 
• 98-86-2 acetophenone 

Downstream Products

• 5676-32-4 α-n-propylstyrene 
• 26452-86-8 3-methyl-2-phenyl-1-pentene 
• 38212-14-5 1-isobutylvinylbenzene 
• 20826-80-6 2-phenylhex-1-ene 
• 5698-49-7 2-phenyl-1-octene 
• 76886-58-3 3-(1-phenylethenyl)cyclohexanone 
• 76886-61-8 4-methyl-5-phenylhex-5-en-2-one 
• 95139-27-8 9-(1-phenylvinyl)anthracene 
• 102360-22-5 5-dimethylamino-1,3-diphenyl-3-penten-2-ol (Z) hydrochloride 
• 907997-09-5 2-phenyl-1,4-pentadien-3-one 
• 446302-83-6 1-N-benzyl-3-phenyl-4-piperidone 
• 1215036-17-1 rac-1-benzyl-4-(hydroxyimino)-3-phenylpiperidine 
• 907997-19-7 2-phenyl-1,4-pentadien-3-ol 
• 17620-97-2 diphenyl-(1-phenylethenyl)phosphine 

Relevant academic research and scientific papers

Development of κ opioid receptor agonists by focusing on phenyl substituents of 4-dimethylamino-3-phenylpiperidine derivatives: Structure-activity relationship study of matrine type alkaloids

A series of new κ opioid receptor (KOR) agonists were developed from the lead compound 4-dimethylamino-1-pentanoylpiperidine (3), a matrine-type alkaloid. Derivatives of 3 were synthesized with a variety of phenyl substituents and evaluated for their anti

RhI-catalyzed benzo/[7+1] cycloaddition of cyclopropyl-benzocyclobutenes and CO by merging thermal and metal-catalyzed C-C bond cleavages

A Rh-catalyzed benzo/[7+1] cycloaddition of cyclopropyl-benzocyclobutenes (CP-BCBs) and CO to benzocyclooctenones has been developed. In this reaction, CP-BCB acts as a benzo/7-C synthon and the reaction involves two C-C bond cleavages: a thermal electrocyclic ring-opening of the four-membered ring in CP-BCB and a Rh-catalyzed C-C cleavage of the cyclopropane ring.

Silicon-Directed Nazarov Reactions II. Preparation and Cyclization of β-Silyl-substituted Divinyl Ketones

Two general methods for the preparation of β-silyl-substituted divinyl ketones have been developed starting from either α,β-unsaturated aldehydes or simple ketones.Anhydrous FeCl3 induces the cyclization to cyclopentenones under mild conditions and in good yields with predictable and complete control over the position of the double bond in the five-membered ring.The observed effects of substituents on rate can be explained by a rate-determining cationic electrocyclization.Silyl substitution has been shown to retard the reaction.

ENEPHOSPHINILATION

A general method is described for the formation of vinylphosphines from arylsulfonylhydrazones.Oxidation of the resulting vinylphosphines yields phosphine oxides.