26460-67-3Relevant articles and documents
Perilla acid methyl ester derivatives containing nitrogen and its preparation and use
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Paragraph 0026; 0027, (2018/04/02)
The invention belongs to the technical field of medicines and relates to a purple perilla methyl rosmarinate nitrogen-containing derivative as well as a preparation method and application thereof, wherein the purple perilla methyl rosmarinate nitrogen-containing derivative has structural characteristics shown in a formula I described in the specification. The invention also relates to pharmaceutically acceptable salt and solvate of the purple perilla methyl rosmarinate nitrogen-containing derivative and a pharmaceutical composition containing the purple perilla methyl rosmarinate nitrogen-containing derivative or pharmaceutically acceptable salt of the purple perilla methyl rosmarinate nitrogen-containing derivative as active ingredients, wherein the pharmaceutically acceptable salt and solvate and the pharmaceutical composition can be used for treating cancer. The purple perilla methyl rosmarinate nitrogen-containing derivative and pharmaceutical salt thereof have good antitumour activities, the preparation method is simple and feasible, and operation is easy.
One-pot chemoenzymatic synthesis of aldoximes from primary alcohols in water
Zambelli, Paolo,Pinto, Andrea,Romano, Diego,Crotti, Elena,Conti, Paola,Tamborini, Lucia,Villa, Raffaella,Molinari, Francesco
, p. 2158 - 2161 (2012/09/22)
A new synthetic method for the one-pot preparation of aldoximes in water was developed; the method is based on the combination of the enzymatic oxidation of primary alcohols to aldehydes using different acetic acid bacteria and in situ condensation of the aldehydes with hydroxylamine.
THE SYNTHESIS OF (-)-SIRENIN, SPERM ATTRACTANT OF THE WATER MOLD ALLOMYCES MACROGYNUS
Kitahara, Takeshi,Horiguchi, Akira,Mori, Kenji
, p. 4713 - 4720 (2007/10/02)
Synthesis of (-)-sirenin 1a, sperm attracting hormone of Allomyces macrogynus was achieved through 10 steps from (-)-perillaldehyde 3.Formation of cyclopropane ring was executed diastereoselectively by the cyclization via intramolecular epoxide opening under carefully controlled condition.