26460-67-3Relevant articles and documents
Perilla acid methyl ester derivatives containing nitrogen and its preparation and use
-
Paragraph 0026; 0027, (2018/04/02)
The invention belongs to the technical field of medicines and relates to a purple perilla methyl rosmarinate nitrogen-containing derivative as well as a preparation method and application thereof, wherein the purple perilla methyl rosmarinate nitrogen-containing derivative has structural characteristics shown in a formula I described in the specification. The invention also relates to pharmaceutically acceptable salt and solvate of the purple perilla methyl rosmarinate nitrogen-containing derivative and a pharmaceutical composition containing the purple perilla methyl rosmarinate nitrogen-containing derivative or pharmaceutically acceptable salt of the purple perilla methyl rosmarinate nitrogen-containing derivative as active ingredients, wherein the pharmaceutically acceptable salt and solvate and the pharmaceutical composition can be used for treating cancer. The purple perilla methyl rosmarinate nitrogen-containing derivative and pharmaceutical salt thereof have good antitumour activities, the preparation method is simple and feasible, and operation is easy.
Methyl Perillate as a Highly Functionalized Natural Starting Material for Terephthalic Acid
Jongedijk, Esmer,van der Klis, Frits,de Zwart, Rozemarijn,van Es, Daan S.,Beekwilder, Jules
, p. 201 - 203 (2018/03/06)
Renewable commodity chemicals can be generated from plant materials. Often abundant materials such as sugars are used for this purpose. However, these lack appropriate functionalities and, therefore, they require extensive chemical modifications before they can be used as commodity chemicals. The plant kingdom is capable of producing an almost endless variety of compounds, including compounds with highly appropriate functionalities, but these are often not available in high quantities. It has been demonstrated that it is possible to produce functionalized plant compounds on a large scale by fermentation in microorganisms. This opens up the potential to exploit plant compounds that are less abundant, but functionally resemble commodity chemicals more closely. To elaborate this concept, we demonstrate the suitability of a highly functionalized plant compound, methyl perillate, as a precursor for the commodity chemical terephthalic acid.
One-pot chemoenzymatic synthesis of aldoximes from primary alcohols in water
Zambelli, Paolo,Pinto, Andrea,Romano, Diego,Crotti, Elena,Conti, Paola,Tamborini, Lucia,Villa, Raffaella,Molinari, Francesco
, p. 2158 - 2161 (2012/09/22)
A new synthetic method for the one-pot preparation of aldoximes in water was developed; the method is based on the combination of the enzymatic oxidation of primary alcohols to aldehydes using different acetic acid bacteria and in situ condensation of the aldehydes with hydroxylamine.
ANTIMICROBIAL AGENT AGAINST BACTERIA, YEAST AND MOULDS
-
Page/Page column 28-29, (2010/02/08)
The invention relates to novel peril acid and alcohol derivatives and to the use of peril acid and alcohol and the derivatives thereof in the form of antimicrobial agents acting against bacteria, yeast and moulds. The inventive agents are used, in particu
THE SYNTHESIS OF (-)-SIRENIN, SPERM ATTRACTANT OF THE WATER MOLD ALLOMYCES MACROGYNUS
Kitahara, Takeshi,Horiguchi, Akira,Mori, Kenji
, p. 4713 - 4720 (2007/10/02)
Synthesis of (-)-sirenin 1a, sperm attracting hormone of Allomyces macrogynus was achieved through 10 steps from (-)-perillaldehyde 3.Formation of cyclopropane ring was executed diastereoselectively by the cyclization via intramolecular epoxide opening under carefully controlled condition.
