2648-66-0Relevant articles and documents
4,4′-Bis(dichloroiodo)biphenyl and 3-(dichloroiodo)benzoic acid: New recyclable hypervalent iodine reagents for vicinal halomethoxylation of unsaturated compounds
Yusubov, Mehman S.,Drygunova, Larisa A.,Zhdankin, Viktor V.
, p. 2289 - 2292 (2007/10/03)
4,4′-Bis(dichloroiodo)biphenyl and 3-(dichloroiodo)benzoic acid are convenient recyclable hypervalent iodine reagents for vicinal chloromethoxylation or iodomethoxylation of unsaturated compounds. The reactivity of these reagents in the reaction of vicinal halomethoxylation is generally similar to dichloroiodobenzene and the advantage of their use is that the reduced forms of these reagents can be easily separated from the reaction mixture and reused for the regeneration of the reagents.
Iodosobenzene dichloride, a convenient reagent for chloro- and iodomethoxylation of double and triple bonds
Yusubov,Yusubova,Filimonov,Ki-Whan, Chi
, p. 902 - 904 (2007/10/03)
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Ozonolysis of substituted 1,2-dichloroethylenes in methanol: products and reaction course
Huh, Tae-Seong,Neumeister, Joachim,Griesbaum, Karl
, p. 3188 - 3191 (2007/10/02)
Ozonolysis of trans-2,3-dichloro-2-butene (5a), of trans-3,4-dichloro-3-hexene (5b), and of 1,2-dichlorocyclohexene in methanol and in solutions of sodium methoxide in methanol have been examined.They afforded in high yields the corresponding ester fragments methyl acetate (6a), methyl propionate (6b), and dimethyl adipate (8) respectively.By trapping with phenylacetylene and formation of 1,1-dichloro-2,2-dimethoxy-2-phenylethane, the presence of methyl hypochlorite in the ozonolysis products was established.A reaction course has been proposed which is in accord with these results.
