26482-34-8Relevant academic research and scientific papers
Synthesis of β-peroxy-lactones using 30% H2O2
Singh, Chandan,Srivastav, Naveen Chandra,Srivastava, Nisha,Puri, Sunil K.
, p. 2757 - 2759 (2005)
Cyclopropyl carbinols 1a-e react with H2O2 in the presence of concd H2SO4 at 0-5°C to furnish the corresponding hydroperoxides 2a-e in 45-82% yields. This efficient trapping of cyclopropylmethyl cations by the hydroperoxy group has been exploited to prepare compounds 14-23, a new series of cyclopropyl substituted β-peroxy- lactones.
Synthesis of 1,2,4-trioxepanes and 1,2,4-trioxanes via Hmediated reaction of tertiary carbinols
Ravi, Makthala,Anand, Devireddy,Maurya, Ranjani,Chauhan, Parul,Naikade, Niraj K.,Shukla, Sanjeev K.,Yadav, Prem P.
, p. 173 - 176 (2013/02/26)
A facile and efficient method for the synthesis of 1,2,4-trioxepanes and 1,2,4-trioxanes from different carbinols having cyclopropyl and phenyl substituents has been developed. The corresponding hydroxyhydroperoxides were synthesized from 30% Hmediated reaction of carbinols in acidic conditions. This method provided access to novel 6,6-diaryl-substituted 1,2,4-trioxanes derived from benzilic acid. Georg Thieme Verlag Stuttgart · New York.
