265651-54-5Relevant academic research and scientific papers
Reaction of nickelocene with 1,3-dimesitylimidazolium chloride
Abernethy, Colin D.,Cowley, Alan H.,Jones, Richard A.
, p. 3 - 5 (2000)
Treatment of nickelocene with 1,3-dimesitylimidazolium chloride affords the corresponding carbene complex, (η5-C5H5)NiCl(carbene) (5). The structure of 5 was determined by X-ray crystallography. The distorted trigonal planar nickel atom is attached to an η5-Cp, a carbene, and a chloride ligand. Compound 5 reacts with MeLi to afford (η5-C5H5)Ni(Me)(carbene).
N-Heterocyclic carbene complexes of cyclopentadienylnickel(II): Synthesis, structure and catalytic activity in styrene polymerization
Buchowicz, W?odzimierz,Kozio?, Andrzej,Jerzykiewicz, Lucjan B.,Lis, Tadeusz,Pasynkiewicz, Stanis?aw,Pecherzewska, Aleksandra,Pietrzykowski, Antoni
, p. 118 - 123 (2006)
Cyclopentadienylnickel(II) complexes with N-heterocyclic carbenes [NiCp(X)(NHC)] (X = Cl, Br or CH3), combined with MAO have been used as catalysts for the polymerization of styrene. The catalytic activity of the systems depended mainly on the
